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Heterocycles from ketenimines. II . Imino-substituted isoxazolidines†

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This article is published in Journal of Heterocyclic Chemistry.The article was published on 1968-12-01. It has received 9 citations till now.

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Synthesis and Reactions of Ketenimines

TL;DR: Ketenimines R1R2CCNR3 were first reported in 1919, but the development of the chemistry of these compounds is of relatively recent origin this paper, and they are becoming of increasing interest as a dehydrating agent for peptide syntheses, as a coreagent in dimethyl sulfoxide oxidations, and as a substrate in the synthesis of heterocycles by condensation with polar multiple bonds and dipolar systems.
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Cycloadditions with Cyclic Seven-Membered Ketene Imines

TL;DR: The cyclic seven-membered ketene imines (8A, 8C) as mentioned in this paper are available by reactions of thiocarbonyl ylides 3 with 2,3-bis(trifluoromethyl)fumaronitrile (4).
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