Journal ArticleDOI
Hexamethylphosphoramide-boron compounds. A new type of boronium cation
JoséL. Vidal,G. E. Ryschkewitsch +1 more
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In this paper, a hexamethylphosphoramide (HPHP) adduct of BF 3 and BCl 3 was shown to be capable of cleaving the boron-halogen bond in amine-haloboranes for the bromine and iodine species.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1976-01-01. It has received 4 citations till now. The article focuses on the topics: Hexamethylphosphoramide.read more
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Synthese, Struktur und einige Reaktionen [N‐(N′,N′,N″,N″‐tetramethyl)‐guanidinyl]‐substituierter Phosphorylverbindungen
TL;DR: In this article, tetramethylguanidinylsubstituierten Phosphorylverbindungen 1−10 wurden durch Umsetzung der entsprechenden PHosphinsaure- and Phosphonsaure -Chloride with N′,N′, N″,N″-Tetramethyl-guanidein (HTMG) or N-Trimethylsilyl-N>,N'',N '',N>-tetramerylguanidiin (TM
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Complexes of hexamethylphosphoramide with mercury(II) salts
JoséL. Vidal,G. E. Ryschkewitsch +1 more
TL;DR: In this article, the isolation and characterization of the complexes of hexamethylphosphoramide and HgCl 2, HgBr 2, Hg(CN) 2 and hg(CF 3 COO) 2, is described.
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The Mechanism of the Reaction of Silver Nitrite with Alkyl Halides. The Contrasting Reactions of Silver and Alkali Metal Salts with Alkyl Halides. The Alkylation of Ambident Anions1,2
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442. The effect of complex-formation by phosphine oxides on their P–O stretching frequencies
TL;DR: In this article, the ingrared spectra of trimethyl- and triphenylphosphine oxide and a number of their complexes with various transition-metal cations were examined, and an explanation in terms of a lowering of the P-O bond order was proposed.
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