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Highlights der Renaissance der Amidometallchemie

Rhett Kempe
- 04 Feb 2000 - 
- Vol. 112, Iss: 3, pp 478-504
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This article is published in Angewandte Chemie.The article was published on 2000-02-04. It has received 66 citations till now.

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Cooperative Aliphatic PNP Amido Pincer Ligands – Versatile Building Blocks for Coordination Chemistry and Catalysis

TL;DR: In this paper, the coordination chemistry of electron-rich metal complexes with the simple aliphatic, anionic diphosphanylamido ligand {N(CH2CH2PR2)2} is covered and compared with other commonly used anionic PEP (E = C, N) pincer ligands.
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Bis(phosphinimino)methanides as ligands in divalent lanthanide and alkaline earth chemistry – synthesis, structure, and catalysis

TL;DR: In this article, the divalent bis(phosphinimino)methanide lanthanide complexes of composition [{(Me3SiNPPh2)2CH}Ln{(Ph2P)2N}(THF)] have been prepared by a salt metathesis reactions of K{CH(PPh2NSiMe3)2} and LnI2.
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Postmetallocene Lanthanide–Hydrido Chemistry: A New Family of Complexes [{Ln{(Me3Si)2NC(NiPr)2}2(μ-H)}2] (Ln=Y, Nd, Sm, Gd, Yb) Supported by Guanidinate Ligands—Synthesis, Structure, and Catalytic Activity in Olefin Polymerization

TL;DR: The new family of Lewis base free hydrido complexes of rare-earth metals supported by guanidinate ligands was synthesized and structurally characterized and revealed that these complexes are dimeric in both solid state and in [D6]benzene.
Journal ArticleDOI

The co-ordination chemistry ofaminotroponiminates

TL;DR: A review of main group and transition metal complexes of N,N-disubstituted and mono-bridged bis(aminotroponiminate)s can be found in this article.
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1,1′-Di(heteroatom)-functionalised ferrocenes as [N,N], [O,O] and [S,S] chelate ligands in transition metal chemistry

TL;DR: This tutorial review describes the main results obtained over the past decade in order to introduce the reader to an exciting field which currently shows particularly rapid development in coordination chemistry.
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