Journal ArticleDOI
Highly dispersed palladium nanoparticles supported on amino functionalized metal-organic frameworks as an efficient and reusable catalyst for Suzuki cross-coupling reaction
Reihaneh Kardanpour,Shahram Tangestaninejad,Valiollah Mirkhani,Majid Moghadam,Iraj Mohammadpoor-Baltork,Ahmad Reza Khosropour,Farnaz Zadehahmadi +6 more
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Palladium nanoparticles (Pd NPs) supported on amino functionalized UiO-66-NH2 (UiO=University of Oslo) metal-organic framework was prepared using a direct anionic exchange method followed by chemical reduction with sodium acetate in methanol.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2014-07-01. It has received 84 citations till now. The article focuses on the topics: Palladium & Coupling reaction.read more
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Catalysis and photocatalysis by metal organic frameworks
TL;DR: The present review summarizes the current state of the art in the use of MOFs as solid catalysts according to the type of site, making special emphasis on the more recent strategies to increase the population of these active sites and tuning their activity, either by adapting the synthesis conditions or by post-synthetic modification.
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Metal-organic frameworks catalyzed C-C and C-heteroatom coupling reactions.
TL;DR: The use of MOFs as catalysts to promote cross-coupling reactions involving organometallic reaction intermediates and catalysis by Lewis acid sites, which are of large synthetic utility due to the high yields achieved, mild conditions and compatibility with other functional groups.
Journal ArticleDOI
Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks
Martino Rimoldi,Ashlee J. Howarth,Matthew R. DeStefano,Lu Lin,Subhadip Goswami,Peng Li,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +8 more
TL;DR: In this article, the advantages of incorporating active species into Zirconium/Hafnium-based MOFs in catalytic applications are discussed. But the authors focus on the use of active species in catalysts.
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Active site engineering in UiO-66 type metal-organic frameworks by intentional creation of defects: a theoretical rationalization
Matthias Vandichel,Julianna Hajek,Frederik Vermoortele,Michel Waroquier,Dirk De Vos,Veronique Van Speybroeck +5 more
TL;DR: In this paper, the function of the modulators under real synthesis conditions is rationalized by constructing free energy diagrams, and a mechanistic pathway is presented for the dehydroxylation process of the hexanuclear Zr cluster.
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Amino-functionalized MOFs combining ceramic membrane ultrafiltration for Pb (II) removal.
TL;DR: Amino-functionalized metal-organic frameworks (MOFs) were combined with ceramic membrane ultrafiltration (CUF) for the first time in adsorptive removal of Pb (II) from wastewater as discussed by the authors.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.
Jasmina Hafizovic Cavka,Søren Jakobsen,Unni Olsbye,Nathalie Guillou,Carlo Lamberti,Silvia Bordiga,Karl Petter Lillerud +6 more
TL;DR: The Zr-MOFs presented in this work have the toughness needed for industrial applications; decomposition temperature above 500 degrees C and resistance to most chemicals, and they remain crystalline even after exposure to 10 tons/cm2 of external pressure.
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Luminescent Metal–Organic Frameworks
TL;DR: This critical review discusses the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules.
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Engineering Metal Organic Frameworks for Heterogeneous Catalysis
TL;DR: In conclusion, MOFs as Host Matrices or Nanometric Reaction Cavities should not be considered as a source of concern in the determination of MOFs’ properties in relation to other materials.
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Enantioselective catalysis with homochiral metal–organic frameworks
TL;DR: Although still in their infancy, homochiral MOFs have clearly demonstrated their utility in heterogeneous asymmetric catalysis, and a bright future is foreseen for the development of practically useful homochirl MOFs in the production of optically pure organic molecules.