Journal ArticleDOI
Hydrothermal synthesis of copper coordination polymers based on molybdates: Chemistry issues
TLDR
In this paper, the formation of self-assembled metal organic hybrid solids from acidified aqueous molybdate solution containing cupric ions and one of the multidentate organic ligands was studied.About:
This article is published in Journal of Molecular Structure.The article was published on 2006-08-30. It has received 16 citations till now. The article focuses on the topics: Metal-organic framework & Coordination polymer.read more
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The Hydrothermal Synthesis of Transition Metal Complex Templated Octamolybdates
TL;DR: In this paper, the influence of the metal complex and temperature of the hydrothermal reaction on the formation of the different hybrid solids built of octamolybdate clusters is discussed, and plausible mechanisms for the self-assembly of the crystals in terms of supramolecular organization between metal complexes and soluble molybdenum precursors in the initial stages of the reaction are provided.
Journal ArticleDOI
Factors dictating the nuclearity/aggregation and acetate coordination modes of lutidine-coordinated zinc(II) acetate complexes.
TL;DR: The reactions of Zn(OAc)(2).2H(2)O with various positional isomers of lutidine were explored with a view to understand the factors responsible for the nuclearity/aggregation and acetate coordination modes of the products.
Journal ArticleDOI
Role of Nonbonding Interactions in the Crystal Growth of Phenazinediamine Tetrahydrate: New Insights into the Occurrence of 2D Water Layers in Crystal Hydrates
TL;DR: In this paper, a single-crystal analysis of 2,3-phenazinediamine tetrahydrate was performed and it revealed the presence of 2D water layers made of hexameric clusters that are exclusively in the chair conformation similar to that found in hexagonal ice.
Journal ArticleDOI
Syntheses and structures of copper(I) complexes based on CunXn (X = Br and I; n = 1, 2 and 4) units and bis(pyridyl) ligands with longer flexible spacer
TL;DR: Evaluated evolvement indicates that the conformation of flexible bis(pyridyl) ligands and the participation of triphenylphosphine (PPh(3)) as a second ligand take an essential role in the framework formation of the Cu(i) complexes.
Journal ArticleDOI
Crystallization of Anderson−Evans Type Chromium Molybdate Solids Incorporated with a Metal Pyrazine Complex or Coordination Polymer
TL;DR: In this paper, five new metal pyrazine complex templated Anderson−Evans cluster-based solids, (Hpyz)[{Co(pyz)2(H2O)2}{CrMo6(OH)6O18}]
References
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Phase annealing in SHELX-90: direct methods for larger structures
TL;DR: In this article, a phase annealing method, related to the simulated-annealing approach in other optimization problems, is proposed and it is shown that it can result in an improvement of up to an order of magnitude in the chances of solving large structures at atomic resolution.
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
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Supramolecular Chemistry: Concepts and Perspectives
TL;DR: From molecular to supramolescular chemistry: concepts and language of supramolecular chemistry, molecular recognition, information, complementarity molecular receptors - design principles and more.
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Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.
Mohamed Eddaoudi,David B. Moler,Hailian Li,Banglin Chen,Theresa M. Reineke,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Consideration of the geometric and chemical attributes of the SBUs and linkers leads to prediction of the framework topology, and in turn to the design and synthesis of a new class of porous materials with robust structures and high porosity.
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Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐Organization
TL;DR: In this article, the authors proposed a self-assembly approach for the generation of a well-defined supramolecular architecture by self-assembling from their components under a given set of conditions.
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