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Journal ArticleDOI

Immiscibility and spinodal decomposition in III/V alloys

Gerald B. Stringfellow
- 02 Dec 1983 - 
- Vol. 65, pp 454-462
TLDR
In this article, the role of growth technique in determining the range of solid compositions which can be produced, the stability of quaternary alloys and the consequences of the miscibility gap and spinodal decomposition on electrical and optical properties of the alloys, and the potential of these alloys for devices.
About
This article is published in Journal of Crystal Growth.The article was published on 1983-12-02. It has received 77 citations till now. The article focuses on the topics: Spinodal decomposition & Miscibility.

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Citations
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Journal ArticleDOI

Quantum dot heterostructures: Fabrication, properties, lasers (Review)

TL;DR: In this paper, a theory of spontaneous formation of semiconductor nanostructures in heteroepitaxial systems was developed and the existence of perfect quantum dots having an atom-like energy spectrum was demonstrated.
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Ordered structures in GaAs0.5Sb0.5 alloys grown by organometallic vapor phase epitaxy

TL;DR: In this paper, electron diffraction measurements on (100) GaAs1−xSbx layers with x≊0.5 grown by organometallic vapor phase epitaxy indicate that ordered phases are formed during growth.
Journal ArticleDOI

On spinodal decomposition in elastically anisotropic epitaxial films of III‐V semiconductor alloys

TL;DR: In this paper, the elastic energy associated with alloy composition modulation in the epitaxial film of a III-V semiconductor alloy on the [001]−substrate is calculated in the analytic form.
Journal ArticleDOI

Thermodynamic aspects of OMVPE

TL;DR: In this article, a simple model is developed which assumes thermodynamic equilibrium to be established at the solid/vapor interface, which can be used to understand the growth rate limiting process, the conditions necessary to grow a single phase III/V material, and the factors determining solid composition.
Journal ArticleDOI

Ordered structures and metastable alloys grown by OMVPE

TL;DR: In this article, it was shown that the relative strain energies of the various ordered structures at the surface and/or kinetic processes occurring during epitaxial growth indicate that such ordered structures are more stable than the disordered solid solution, but less stable than other ordered structures.
References
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Journal ArticleDOI

On spinodal decomposition

TL;DR: In this article, the stability of a solid solution to all infinitesimal composition fluctuations is considered, taking surface tension and elastic energy into account, and it is found that for infinite isotropic solids, free from imperfections, the spinodal marks the limit of metastability to such fluctuations only if there is no change in molar volume with composition.
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Calculation of ternary and quaternary III–V phase diagrams

TL;DR: In this paper, a simple solution model with Ω=a−bT was used to describe the liquid phase and the solid phase was adequately described using the regular solution model.
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Miscibility gaps in quaternary III/V alloys

TL;DR: In this article, the critical temperatures for all III/V quaternary alloys of the type AxB1-xCyD1-y involving Al, Ga, and In combined with P, As, and Sb were derived using both the DLP model and regular solution model.
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The importance of lattice mismatch in the growth of GaxIn1−xP epitaxial crystals

TL;DR: In this paper, the importance of lattice-parameter mismatch between the GaAs substrate and the GaxIn1−xP epitaxial layer on crystal growth and properties has been investigated.
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Composition modulation in liquid phase epitaxial InxGa1−xAsyP1−y layers lattice matched to InP substrates

TL;DR: In this article, a quasiperiodic variation of a strain contrast, though very light in some cases, is always observed in the 〈100〉 and 》010〉 directions in that composition range, and never outside.