Journal ArticleDOI
Inorganic nitrogen fixation. Nitrogen compounds of the transition metals
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This article is published in Accounts of Chemical Research.The article was published on 1968-12-01. It has received 44 citations till now. The article focuses on the topics: Fixation (surgical) & Nitrogen fixation.read more
Citations
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Cyclometalated phosphine-based pincer complexes: Mechanistic insight in catalysis, coordination, and bond activation
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Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals
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Intramolecular aromatic substitution in transition metal complexes
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The preparation, reactions and structure of bis[bis(tricyclohexylphosphine)nickel] dinitrogen, {[(C6H11)3P]2Ni}2N2
TL;DR: In this article, the dinitrogen complex was determined by X-ray crystallography from 5977 reflections using an automatic diffractometer, and refined anisotropicically for all 80 atoms to a final R-value of 11%.
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Alkyl− and Aryl−Oxygen Bond Activation in Solution by Rhodium(I), Palladium(II), and Nickel(II). Transition-Metal-Based Selectivity
Milko E. van der Boom,Shyh-Yeon Liou,Yehoshoa Ben-David,and Linda J. W. Shimon,David Milstein +4 more
TL;DR: In this article, a metal insertion into the strong sp2−sp3 aryl−O bond was shown to occur directly, with no intermediacy of C−H activation or insertion into adjacent weaker ArO−CH3 bond.
References
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Oxygen-Carrying Properties of a Simple Synthetic System
TL;DR: An iridium compound, chloro-carbonyl-bis(triphenylphosphine)-iridium, in solution, takes up molecular oxygen—one molecule per metal atom—which is subsequently recovered by reducing the pressure.
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Nitrogen Fixation by Transition Metal Complexes
M. E. Vol'pin,Vladimir B. Shur +1 more
TL;DR: In this article, it has been shown that small amounts of ammonia can form on prolonged cathodic reduction of nitrogen (or reduction by stannous chloride) in the presence of aqueous solutions of molybdate and tungstate ions.
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Ruthenium complexes containing molecular nitrogen
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Iridium Complexes of Molecular Nitrogen
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Binuclear Ion Containing Nitrogen as a Bridging Group
TL;DR: Solid [(NH3)5RuN2Ru(NH3]5] (BF4)4 has been prepared, and its ultraviolet and infrared spectra are reported.