Kinetics and mechanisms of electrochemical reactions on platinum with solutions of iodine-sodium iodide in acetonitrile
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In this paper, the anodic and cathodic current/voltage curves are characterized by two well defined waves, and the total reactions related to the first and second anodic waves are respectively 3I− = I3− + 2 e and 2I3− = 3I2+2 e, while the reverse reactions represent the second and first cathodic waves respectively.About:
This article is published in Electrochimica Acta.The article was published on 1969-04-01 and is currently open access. It has received 107 citations till now. The article focuses on the topics: Rotating disk electrode & Electrochemistry.read more
Citations
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Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells
Anneke Hauch,Andreas Georg +1 more
TL;DR: In this paper, a dye-sensitized solar cell (DSC) was characterized using electrochemical impedance spectroscopy (EIS) to characterize the electrolyte/platinum interface of a DSC.
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Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces
Shane Ardo,Gerald J. Meyer +1 more
TL;DR: A critical review of light-driven interfacial charge-transfer reactions of transition-metal compounds anchored to mesoporous, nanocrystalline TiO2 (anatase) thin films is described.
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Charge recombination in dye-sensitized nanocrystalline tio2 solar cells
TL;DR: In this article, a charge recombination between dye-sensitized nanocrystalline TiO2 electrodes and the I3/I-couple in nonaqueous solution is described.
Journal ArticleDOI
Counter-electrode function in nanocrystalline photoelectrochemical cell configurations
TL;DR: In this paper, a dye-sensitized TiO 2 nanocrystalline solar cell utilizing the iodide/tri-iodide redox mediator was used to scrutinize CE performance, which was coupled by experimental exploration of catalyst materials and different design options.
Journal ArticleDOI
Investigation of influence of redox species on the interfacial energetics of a dye-sensitized nanoporous TiO2 solar cell
TL;DR: In this paper, a dye-sensitized nanoporous TiO2 solar cells are studied under influences of light intensity, redox couple concn., temp., different cations and water in the nonaq. soln.
References
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Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
Journal ArticleDOI
Kinetics of oxygen evolution and dissolution on platinum electrodes
TL;DR: In this paper, the reaction mechanism in acid solution includes the primary water discharge as the rate-controlling step, while in alkaline solution, the mechanism changes and, for the same path, the primary discharge of OH− becomes the rate controlling step.
Journal ArticleDOI
Studies on the Chemistry of Halogen and of Polyhalides. XIII. Voltammetry of Iodine Species in Acetonitrile
Journal ArticleDOI
Voltammetric evaluation of the stability of trichloride, tribromide, and triiodide ions in nitromethane, acetone, and acetonitrile
TL;DR: In this paper, the formation constants of trichloride, tribromide, and triiodide ions in acetonitrile and triconitrile have been evaluated from electrochemical data.
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