Journal ArticleDOI
Mechanism of Grignard reagent formation. The surface nature of the reaction
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This article is published in Accounts of Chemical Research.The article was published on 1989-03-01. It has received 91 citations till now. The article focuses on the topics: Reaction mechanism.read more
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Recent Advances in the Baylis−Hillman Reaction and Applications
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Recent contributions from the Baylis-Hillman reaction to organic chemistry.
TL;DR: Acyclic activated alkenes/ alkynes and Asymmetric Baylis-Hillman Reaction: Earlier Developments 5495.
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Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent
Alain Krief,A.‐M. Laval +1 more
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Mimicking Aspects of Heterogeneous Catalysis: Generating, Isolating, and Reacting Proposed Surface Intermediates on Single Crystals in Vacuum.
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Strategies To Prepare and Use Functionalized Organometallic Reagents
TL;DR: Efficient and general preparations of zinc and magnesium organometallic reagents, as well as their most practical and useful reactions, are presented in this Perspective.
References
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Electron spin resonance studies of transient alkyl radicals
TL;DR: In this article, the ESR lines are found to be narrow; considerable fine structure is observable, permitting positive assignment of the radical species, and accurate hyperfine constants are reported for 21 alkyl and cycloalkyl radicals, including several deuterated species.
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Preparation of highly reactive metal powders and their use in organic and organometallic synthesis
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Preparation of highly reactive metal powders. New procedure for the preparation of highly reactive zinc and magnesium metal powders
TL;DR: In this paper, the reformatsky reaction, the Grignard reaction, and cyclopropanation with dibromomethane are described, as well as applications to the reformatization of metal powders.