Journal ArticleDOI
Mechanism of Oxidative Decarboxylation of α-Hydroxy Acids by Bromine Water. Part II. Oxidation in Acidic Medium. A Comparison with the HOBr – Oxalic Acid Reaction
Judith M. Pink,Ross Stewart +1 more
TLDR
In this paper, it was shown that α-hydroxy acids by acidic bromine water is similar to the oxalic acid-bromine-water reaction, in both cases HOBr is the oxidant and the undissociated form of...Abstract:
The oxidative pattern of α-hydroxy acids by acidic bromine water is shown to be similar to the oxalic acid – bromine water reaction. In both cases HOBr is the oxidant and the undissociated form of ...read more
Citations
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Journal ArticleDOI
A kinetic study of the oxidation of α‐hydroxy acids and α‐hydroxy ketones by potassium bromate
TL;DR: In this article, a mechanism involving a slow formation of a bromate ester of the α-hydroxy acid followed by a fast decomposition is proposed, which explains the kinetic data for the oxidation of benzoin.
Journal ArticleDOI
Conversion of Plant Secondary Metabolites upon Fermentation of Mercurialis perennis L. Extracts with two Lactobacteria Strains
TL;DR: This work investigated the metabolic conversion of constituents from Mercurialis perennis L. extracts, which were prepared for such applications, and observed an almost complete conversion of the genuine piperidine-2,6-dione alkaloids hermidine quinone and chrysohermidin, while novel metabolites such as methylhermid in (6) and methylherMidin quin one (7) were formed.
Journal ArticleDOI
Kinetics of oxidation of isopropyl alcohol by aóueous iodine
TL;DR: In this paper, the first and zero order with respect to substrate and iodine, respectively, were investigated for isopropyl alcohol by aqueous iodine at pH 9.18.
Journal ArticleDOI
Kinetics and mechanism of the oxidation of some α-hydroxy acids by hexamethylenetetramine-bromine
Dimple Garg,Seema Kothari +1 more
TL;DR: In this paper, it is proposed that hexamethylenetetetramine-bromine (HABR) itself is the reactive oxidizing species, and a mechanism involving transfer of a hydride ion from the acid to the oxidant is proposed.
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