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Journal ArticleDOI

Mechanisms of Arsenic Adsorption on Amorphous Oxides Evaluated Using Macroscopic Measurements, Vibrational Spectroscopy, and Surface Complexation Modeling.

Sabine Goldberg, +1 more
- 01 Feb 2001 - 
- Vol. 234, Iss: 1, pp 204-216
TLDR
In this study in situ Raman and Fourier transform infrared (FTIR) spectroscopic methods were combined with sorption techniques, electrophoretic mobility measurements, and surface complexation modeling to study the interaction of As(III) and As(V) with amorphous oxide surfaces.
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This article is published in Journal of Colloid and Interface Science.The article was published on 2001-02-01. It has received 1181 citations till now. The article focuses on the topics: Amorphous solid & Oxide.

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Citations
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Journal ArticleDOI

Arsenic removal from water/wastewater using adsorbents—A critical review

TL;DR: Strong acids and bases seem to be the best desorbing agents to produce arsenic concentrates, and some commercial adsorbents which include resins, gels, silica, treated silica tested for arsenic removal come out to be superior.
Journal ArticleDOI

Comparison of arsenic(V) and arsenic(III) sorption onto iron oxide minerals: implications for arsenic mobility.

TL;DR: The sorption data indicate that, under most of the chemical conditions investigated in this study, reduction of As(V) in the presence of HFO or goethite would have only minor effects on or even decrease its mobility in the environment at near-neutral pH conditions.
Journal ArticleDOI

Aquatic arsenic: Toxicity, speciation, transformations, and remediation

TL;DR: The number of different arsenic species found in environmental samples and an understanding of the transformations between arsenic species has increased over the past few decades as a result of new and refined analytical methods.
Journal ArticleDOI

Arsenic(V) removal from groundwater using nano scale zero-valent iron as a colloidal reactive barrier material.

TL;DR: The effects of competing anions revealed that HCO3-, H4SiO4(0), and H2PO4(2-) are potential interfering agents in the As(V) adsorption reaction.
Journal ArticleDOI

Competitive Adsorption of Arsenate and Arsenite on Oxides and Clay Minerals

TL;DR: In this paper, a constant capacitance model was used to fit the arsenate and arsenite adsorption envelopes to obtain values of the intrinsic As surface complexation constants.
References
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Surface Complexation Modeling: Hydrous Ferric Oxide

TL;DR: In this article, the generalized two-layer model is used to analyze the Coulombic effect of Hydrous Ferric Oxide, and anion and cation sorsption on HFOs are investigated.
Journal ArticleDOI

Surface ionization and complexation at the oxide/water interface

TL;DR: In this article, a method for determination of intrinsic ionization and complexation constants of oxide surface sites from potentiometric titration data is reported using these experimental properties and the stoichiometry of surface reactions, surface charge, σo, adsorption density, Γi, and diffuse layer potentials, ψd, at the oxide/water interface.
Journal ArticleDOI

Arsenic poisoning of Bangladesh groundwater

TL;DR: Sedimentological study of the Ganges alluvial sediments shows that the arsenic derives from the reductive dissolution of arsenic-rich iron oxyhydroxides, which in turn are derived from weathering of base-metal sulphides.
Journal ArticleDOI

Arsenite and Arsenate Adsorption on Ferrihydrite: Kinetics, Equilibrium, and Adsorption Envelopes

TL;DR: In this paper, the authors compared the adsorption behavior of arsenite and arsenate on ferrihydrite, under carefully controlled conditions, with regard to adaption kinetics and the influence of pH.
Journal ArticleDOI

Adsorption of arsenite and arsenate on amorphous iron hydroxide

TL;DR: In this paper, the authors measured the adsorption isotherms in solutions with ionic strengths of 0.01 at 25°C and measured over the arsenite and arsenate concentration range 10−7−10−3 M and the pH range 4−10.
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