Journal ArticleDOI
Molten lithium nitrate-potassium nitrate eutectic: some reactions of copper(ii) and of metallic silver
H. Frouzanfar,D.H. Kerridge +1 more
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TLDR
In this paper, it was shown that metallic silver reacts to a much larger extent with a Lux-Flood acid (pyrosulphate) in solution than with nitrogen dioxide giving support to the nitryl cation as the acidic species in nitrate melts.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1979-01-01. It has received 11 citations till now. The article focuses on the topics: Copper & Iodide.read more
Citations
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Journal ArticleDOI
Synthesis of solid materials in molten nitrates
TL;DR: In this paper, the synthesis of inorganic compounds in molten nitrates is discussed and several examples of this molten salt synthesis approach are given with the objective of optimising textural properties for catalytic applications.
Journal ArticleDOI
Copper nitrate-mediated synthesis of 3-aryl isoxazolines and isoxazoles from olefinic azlactones.
Yifan Lin,Ke Zhang,Mingchun Gao,Zheyi Jiang,Jiajie Liu,Yurui Ma,Haoyu Wang,Qitao Tan,Junjie Xiao,Bin Xu,Bin Xu +10 more
TL;DR: The given approach features a new mode of cycloaddition from olefinic azlactones, copper nitrate and unsaturated compounds with wide substrate scope, good functional group tolerance and operational simplicity.
Journal ArticleDOI
Thermal stability and solubility of alkaline earth nitrates and chromates in nitrate melts
Hadi M. A. Abood,D.H. Kerridge +1 more
TL;DR: In this paper, the same authors determined the solubility values for these nitrates and for calcium and potassium chromates Latent heat of fusion values were derived for the latter two compounds.
Journal ArticleDOI
From Alkenes to Isoxazolines via Copper-Mediated Alkene Cleavage and Dipolar Cycloaddition.
TL;DR: An unprecedented copper-mediated anion transformation is reported, along with selective C═C double bond cleavage and dipolar cycloaddition reaction from simple alkenes and inexpensive copper nitrate, which indicates a novel ionic pathway for alkene cleavage.
Journal ArticleDOI
Products of reactions of Mo and Zr compounds in molten nitrate
TL;DR: In this paper, the physicico-chemical properties of the products were studied vs. reaction temperature, nature of the alkali-metal cation and Mo reactant, and reaction temperature was of primary importance in determining the composition and structure of the product.
References
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Journal ArticleDOI
Studies of Acid—Base Equilibria in Molten Alkali Nitrates
Journal ArticleDOI
A study of the nitrate ion dissociation in fused nitrates
Roger N. Kust,Frederick R. Duke +1 more
Journal ArticleDOI
Standard electrode potentials of the iodine-iodide system in molten (Li,K)NO3
TL;DR: In this paper, the standard potentials of the redox couples involving I 2, I −, and I 3 − in molten (Li,K)NO 3 between 435 and 490°K have been determined.
Journal ArticleDOI
Molten lithium-potassium nitrate: The reactions of some halogen compounds
D.A. Habboush,D.H. Kerridge +1 more
TL;DR: In this paper, the stoichiometry of the formation of iodide in pure melts and in dichromate melt solutions was determined, tri-iodide ions being the product in the presence of excess iodide.
Related Papers (5)
Precipitation of Silver(I) Halides in Molten Lithium Nitrate-Potassium Nitrate Eutectic
H. Ti Tien,George W. Harrington +1 more
Molten lithium nitrate-potassium nitrate eutectic: Reaction of some compounds of zinc
D.H. Kerridge,J. Cancela Rey +1 more
Molten sodium-potassium nitrite eutectic: the reactions of some compounds of silver
D.H. Kerridge,S.A. Tariq +1 more