Journal ArticleDOI
Nonspectroscopic interelement interferences in inductively coupled plasma mass spectrometry
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This article is published in Analytical Chemistry.The article was published on 1988-07-15. It has received 251 citations till now. The article focuses on the topics: Inductively coupled plasma mass spectrometry & Mass spectrometry.read more
Citations
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Journal ArticleDOI
Determination of the 10Be half-life by multicollector ICP-MS and liquid scintillation counting
TL;DR: In this article, a new method was designed and used for determining the half-life of the isotope 10 Be, based on accurate 10 Be/ 9 Be measurements of 9 Be-spiked solutions of a 10 Be-rich master solution using multicollector ICP mass spectrometry (MC-ICP-MS) and liquid scintillation counting (LSC) using the CIEMAT/NIST method for determining activity concentrations of the solutions whose 10 Be concentrations were determined by mass spectra.
Journal ArticleDOI
Analytical Methods for Non-Traditional Isotopes
Francis Albarède,Brian L. Beard +1 more
TL;DR: In this paper, the analytical methods employed for making high precision isotope ratio measurements that preserve naturally occurring mass-dependent isotopic variations are devoted to the analytical issues that make mass analysis of nontraditional isotopes challenging and unique.
Journal ArticleDOI
Interferences in inductively coupled plasma mass spectrometry. A review
E. Hywel Evans,Jeffrey J. Giglio +1 more
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Precision and accuracy in isotope ratio measurements by plasma source mass spectrometry
TL;DR: The mass discrimination of ICP-MS is strongly dependent on the potential of the different lenses of the ion optics and on the ion current flow as mentioned in this paper, which may also contribute to the total mass bias.
Journal ArticleDOI
Inductively Coupled Plasma Mass Spectrometry: Introduction to Analytical Aspects.
TL;DR: Clinical scientists should be aware of the analytical aspects of ICP-MS, as well as the potential for both spectroscopic and non-spectroscopic interference, and strategies that can be employed to eliminate or mitigate these issues.
References
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Journal ArticleDOI
Mass spectrometry of inductively coupled plasmas
TL;DR: In this article, the ICP with MS shows promise of extending the sensitivity and selectivity of MS to elemental analysis of solutions, including the use of ICP as an element and isotope selective detector for chromatography, flow injection analysis, laser ablation, and other sample introduction techniques; fundamental studies of ionization other basic processes in ICP; detection of halogens and perhaps other elements as negative ions; and auxiliary ionization of neutral analyte atoms formed from ICP ions that have recombined with electrons during the extraction process.
Journal ArticleDOI
Suppression of analyte signal by various concomitant salts in inductively coupled plasma mass spectrometry
Jose A. Olivares,Robert S. Houk +1 more
TL;DR: In this paper, the interference on the ionization of cobalt by five salts, NaCl, MgCl/sub 2/, NH/sub 4/I, NH/Sub 4/Br, and NH/ Sub 4/Cl, is first looked at theoretically, and subsequently the theoretical trends are established experimentally by mass spectrometry (ICP-MS).
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Inductively coupled plasma source mass spectrometry using continuum flow ion extraction
Alan L. Gray,Alan R. Date +1 more
TL;DR: An inorganic mass spectrometry system that uses an atmospheric pressure inductively coupled plasma (ICP) as an ion source is described in this article, where a quadrupole mass analyser is used with a pulse counting ion detector followed by a multi-channel scaler data system.
Journal ArticleDOI
Disproportionation and ECE mechanisms—I. Theoretical analysis. Relationships for linear sweep voltammetry☆
TL;DR: In this article, a general mechanism involving two successive charge-transfer steps coupled with acid-base reactions is considered, and theoretical relationships allowing the kinetic analysis of such reaction schemes by linear sweep voltammetry are established.
Journal ArticleDOI
Ece and disproportionation
TL;DR: In this paper, the effect of the experimental parameters: rate and equilibrium constants, sweep rate and initial concentration can be rationalized with the use of only two dimensionless parameters in the general case.
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Suppression of analyte signal by various concomitant salts in inductively coupled plasma mass spectrometry
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