Nuclear Magnetic Interactions in the HF Molecule

TLDR: In this article, a scalar term AI·S resulting from the indirect electron-coupled interaction between the two nuclei removes all the discrepancies between the calculated and observed decay times.

Abstract: Magnetic relaxation times of hydrogen and fluorine in anhydrous hydrofluoric acid cannot be accounted for on the assumption of a pure dipole‐dipole interaction between the hydrogen and the fluorine nuclei in the same molecule. However, the introduction, in the Hamiltonian, of a scalar term AI·S resulting from the indirect electron‐coupled interaction between the two nuclei removes all the discrepancies between the calculated and observed decay times. Although the splitting due to this scalar term is smeared out by the rapid chemical exchange of the protons with the traces of water present in the acid, the nuclear Overhauser effect provides the extra parameter required to separate the dipole‐dipole interaction from the scalar interaction and to calculate separately the scalar splitting and the exchange rate of the protons. The value obtained for the splitting is A/h=615 cps.The same method has been applied to investigate the structure of the HF molecule in solutions. The experimental results can be explain...