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Journal ArticleDOI

On the thermal decomposition of the zinc(II) hydroxide chlorides Zn5(OH)8Cl2·H2O and Β-Zn(OH)Cl

TLDR
In this article, several reaction schemes are proposed to account for thermal decomposition reactions undergone by both zinc hydroxide chlorides and β-Zn(OH)Cl materials.
Abstract
The thermal decomposition of Zn5(OH)8Cl2·H2O and β-Zn(OH)Cl materials under several experimental conditions has been studied by thermal analysis, X-ray powder diffraction and X-ray high-temperature powder diffraction techniques. Several reaction schemes are proposed to account for thermal decomposition reactions undergone by both zinc hydroxide chlorides.

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Citations
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Journal ArticleDOI

XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions

TL;DR: In this paper, X-ray photoelectron spectroscopy (XPS) allowed to calculate the modified Auger parameters (α ′) thereof to 2010.2.4, 2009.3.7, and 2009.4.7.
Journal ArticleDOI

The role of anhydrous zinc nitrate in the thermal decomposition of the zinc hydroxy nitrates Zn5(OH)8(NO3)2·2H2O and ZnOHNO3·H2O

TL;DR: In this paper, it was shown that in the thermal decomposition of Zn5(OH)8(NO3)2·2H2O an anhydrous zinc nitrate intermediate is also involved.
Journal ArticleDOI

Influence of the Precursors and Chemical Composition of the Solution on the Properties of ZnO Thin Films Grown by Spray Pyrolysis

TL;DR: In this paper, the effect of solution composition on the properties of ZnO thin films grown by spray pyrolysis has been investigated and it was found that organic salts are preferable over inorganic ones such as chlorides and nitrates.
Journal ArticleDOI

Evidence for the formation of anhydrous zinc acetate and acetic anhydride during the thermal degradation of zinc hydroxy acetate, Zn5(OH)8(CH3CO2)2·4H2O to ZnO

TL;DR: In this paper, it has been demonstrated by FTIR analysis that the interaction of the acetate anion with the matrix cation is ionic, contrary to previous reports, and the anhydrous zinc acetate is finally lost, at temperatures below 400°C, as acetic anhydride, (CH 3 CO) 2 O.
References
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Journal ArticleDOI

Microstructural characterization of nanocrystals of ZnO and CuO obtained from basic salts

TL;DR: In this paper, X-ray powder diffraction was carried out using the Rietveld method and convolutive Xray line broadening analysis, which indicated very small crystallite sizes.
Journal ArticleDOI

Studies on metal hydroxy compounds. I. Thermal analyses of zinc derivatives ϵ-Zn(OH)2, Zn5(OH)8Cl2.H2O, β-ZnOHCl, and ZnOHF

TL;DR: In this paper, the replacement of a hydroelectric power station with a thermal sensor is discussed. But the results show that the replacement is not suitable for all applications, and the results are limited to the case of β-ZnOHCl and ZnOHF.
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