Journal ArticleDOI
Oxidation of Alcohols with H2O2 Catalyzed by Titanium Silicalite-1
F. Maspero,U. Romano +1 more
TLDR
In this article, secondary and secondary alcohols are oxidised by H2O2 in the presence of titanium silicalite-1 to carbonylic compounds, and the reaction pattern is consistent with a process taking place essentially inside the zeolite channels.About:
This article is published in Journal of Catalysis.The article was published on 1994-04-01. It has received 104 citations till now. The article focuses on the topics: Primary alcohol & Alcohol oxidation.read more
Citations
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Journal ArticleDOI
Green oxidation with aqueous hydrogen peroxide
TL;DR: Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst in an economically, technically, and environmentally satisfying manner.
Journal ArticleDOI
Lewis acids as catalysts in oxidation reactions: from homogeneous to heterogeneous systems.
TL;DR: This review is focused on the use of solid Lewis acids to promote catalytic oxidations, and the core of the review is organized to show the evolution from the simplest strategy for heterogeneizing homogeneous catalysts, to the more elaborate ones in which the active sites are part of the solid structure.
Journal ArticleDOI
New developments in catalytic alcohol oxidations for fine chemicals synthesis
TL;DR: New developments in liquid phase catalytic oxidations of alcohols with O2 and H2O2 as the primary oxidant are reviewed in this paper, where homogeneous and heterogeneous catalysts are discussed and compared and emphasis is placed on methods having broad utility for the synthesis of fine chemicals.
Journal ArticleDOI
Direct synthesis of hydrogen peroxide from hydrogen and oxygen: An overview of recent developments in the process
TL;DR: In this paper, the role of protons (H+) and halide ions in promoting the selectivity of direct H2O2 synthesis is examined in detail, and the potential hazards associated with H2/O2 mixtures and poor selectivity are discussed.
Book ChapterDOI
Microporous Crystalline Titanium Silicates
TL;DR: In this paper, the authors focused on the microporous crystalline titanium silicates and their catalytic properties in H2O2 oxidation reactions and attributed the unusual properties of titanium silicalites have been attributed to the presence of TiIV in framework positions of the SiO2 lattice.
Related Papers (5)
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite
M. G. Clerici,P. Ingallina +1 more