Journal ArticleDOI
Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite
TLDR
In this article, the epoxidation of propylene with hydrogen peroxide in the liquid phase, in the presence of titanium silicalite catalyst (TS-1), is described.About:
This article is published in Journal of Catalysis.The article was published on 1991-05-01. It has received 681 citations till now. The article focuses on the topics: Propylene oxide & Epoxide.read more
Citations
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Chemical Routes for the Transformation of Biomass into Chemicals
TL;DR: Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481 4.2.1.
Journal ArticleDOI
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
TL;DR: The utilization of CO(2) as a building block may represent an interesting approach to synthetic methodologies less intensive in carbon and energy.
Journal ArticleDOI
Metal-Catalyzed Epoxidations of Alkenes with Hydrogen Peroxide
Benjamin S. Lane,Kevin Burgess +1 more
TL;DR: Metal Oxides Generated in Situ 2461 4.1.
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Heterogeneous gold-based catalysis for green chemistry: low-temperature CO oxidation and propene oxidation.
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Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates
TL;DR: In this article, a review of recent developments for the epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates is presented, which can be classified into two groups according to the structural and mechanistic aspects: (i) catalyst precursors of peroxotungstate or peroxomolybdate species and (ii) oxidatively and hydrolytically stable transition-metal-substituted polyoxmetalates.
References
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Journal ArticleDOI
A new, effective catalytic system for epoxidation of olefins by hydrogen peroxide under phase-transfer conditions
TL;DR: In this article, a nouveau catalyseur is constitue par une association d'ions tungstate et phosphate dans des conditions acides, in which tungstane and phosphate are used.
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Epoxydation des olefines par les complexes peroxydiques covalents du molybdene—VI
TL;DR: In this article, a mecanisme aprotique 1-3 dipolaire de la formation d'epoxyde is proposed, which is based on the reaction of the olefiniques.
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Metal-catalyzed epoxidation of olefins with organic hydroperoxides: I. A comparison of various metal catalysts
TL;DR: In this paper, it was shown that an active epoxidation catalyst should be both a weak oxidant and a fairly strong Lewis acid, and that these requirements are best met by compounds of certain metals in high oxidation states.
Journal ArticleDOI
Mechanism of the molybdenum and vanadium catalyzed epoxidation of olefins by alkyl hydroperoxides
A. O. Chong,K. B. Sharpless +1 more
Related Papers (5)
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite
M. G. Clerici,P. Ingallina +1 more