scispace - formally typeset
Journal ArticleDOI

Oxidative Coupling of Methane to Higher Hydrocarbons

J. S. Lee, +1 more
- 01 Jun 1988 - 
- Vol. 30, Iss: 2, pp 249-280
TLDR
In this paper, a possible route is oxidative dimerization of methane followed by oligomerization of the C2 products, which can be used as feedstock for the production of chemicals or liquid fuels.
Abstract
Natural gas is an abundant resource in various parts of the world. Methane is the major component of natural gas, often comprising over 90 mol% of the hydrocarbon fraction of the gas. Methane itself is primarily used as a fuel, while the nonmethane components can be separated and used as feedstocks for the production of chemicals or liquid fuels. In many cases, however, natural gas reserves are found in locations distant from their place of utilization. Since it is not generally economical to transport liquefied natural gas, efficient methods are needed to convert methane into transportable liquid products. A possible route is oxidative dimerization of methane followed by oligomer-ization of the C2 products.

read more

Citations
More filters
Journal ArticleDOI

New catalytic routes for syngas and hydrogen production

TL;DR: In this paper, a review summarizes different catalytic options for the production of syngas and hydrogen starting from simple hydrogen-containing molecules, focusing on new direct catalytic alternatives in natural gas conversion.
Journal ArticleDOI

Catalysts for combustion of methane and lower alkanes

TL;DR: In this paper, a review of the use of catalysts for methane combustion in high temperature natural gas-turbines can be found, where a large amount of work has been undertaken to develop catalysts both for controlling methane emission as well as for generating power.
Journal ArticleDOI

Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry

TL;DR: Recent advances in the development of new catalytic materials or novel catalytic systems for challenging oxidation reactions, which are important from the viewpoint of green and sustainable chemistry and still remain challenging, are summarized.
Journal ArticleDOI

Current understanding of the growth of carbon nanotubes in catalytic chemical vapour deposition

TL;DR: In the field of nanotube synthesis, catalytic chemical vapour deposition (CVD) is the prevailing synthesis method of carbon nanotubes as discussed by the authors, due to its higher degree of control and its scalability.
Journal ArticleDOI

Conversion of Methane by Oxidative Coupling

TL;DR: In this article, the conversion of Methane by Oxidative Coupling is discussed. But it is not discussed in detail in this paper, nor is it discussed in this article.
References
More filters
Journal ArticleDOI

Synthesis of ethylene via oxidative coupling of methane: I. Determination of active catalysts

TL;DR: The most active catalysts for C2 formation were the oxides of Sn, Pb, Sb, Bi, Tl, Cd and Mn, while Li, Mg, Zn, Ti, Zr, Mo, Fe, Cr, W, Cu, Ag, Pt, Ce, V, B and Al showed little or no activity.
Journal ArticleDOI

Formation of gas-phase methyl radicals over magnesium oxide

TL;DR: In this article, the EPR spectroscopy was used to analyze the initial activity of MgO at temperatures of approximately 500/sup 0/C and showed that methyl radicals were produced on the surface, released into the gas phase, and trapped downstream in a solid argon matrix.
Journal ArticleDOI

Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide

TL;DR: In this paper, it was shown that lithium-doped magnesium oxide (Li/MgO) in the presence of O2 has high activity for abstracting H from CH4 to form ·CH3 radicals.
Book ChapterDOI

Characterization and Reactivity of Molecular Oxygen Species on Oxide Surfaces

TL;DR: This chapter discusses the characterization and reactivity of mononuclear oxygen species on oxide surfaces and there is evidence from the examples for some of the species that are stable at much higher temperatures and may play an important role in catalytic reactions.
Related Papers (5)