Journal ArticleDOI
Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen.
About:
This article is published in Journal of the American Chemical Society.The article was published on 2001-08-01. It has received 290 citations till now. The article focuses on the topics: Palladium.read more
Citations
More filters
Journal ArticleDOI
Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.
TL;DR: A review of palladium-catalyzed coupling of CH bonds with organometallic reagents through a PdII/Pd0 catalytic cycle can be found in this paper.
Journal ArticleDOI
Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
TL;DR: Enantioselective PdII-catalyzed functionalization of alkenes has experienced considerably less success than have many other classes of enantiOSElective transformations, despite the extensive history of the Wacker process and related oxidation reactions.
Journal ArticleDOI
Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit
TL;DR: In den letzten zehn Jahren wurde die palladiumkatalysierte C-H-Aktivierung/C-C-Kupplung zu einer vielversprechenden katalytischen Umwandlung entwickelt as mentioned in this paper.
Journal ArticleDOI
Hydroxyapatite-Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Use of Molecular Oxygen
TL;DR: The present Pd catalyst does not require additives to complete the catalytic cycle, and the diameters of the generated Pd nanoclusters can be controlled upon acting on the alcohol substrates used.
Journal ArticleDOI
Efficiency in nonenzymatic kinetic resolution.
Edwin Vedejs,Mara Jure +1 more
TL;DR: The story of kinetic resolution from the early discoveries through fascinating historical milestones and conceptual developments is followed, and a focus on modern techniques that maximize efficiency is closed.
References
More filters
Journal ArticleDOI
Green, catalytic oxidation of alcohols in water
TL;DR: A water-soluble palladium(II) bathophenanthroline complex is a stable recyclable catalyst for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic water-alcohol system.
Journal ArticleDOI
Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity
Víctor S. Martín,Scott S. Woodard,Tsutomu Katsuki,Yasuhiro Yamada,Masonari Ikeda,K. Barry Sharpless +5 more
Journal ArticleDOI
New developments in catalytic alcohol oxidations for fine chemicals synthesis
TL;DR: New developments in liquid phase catalytic oxidations of alcohols with O2 and H2O2 as the primary oxidant are reviewed in this paper, where homogeneous and heterogeneous catalysts are discussed and compared and emphasis is placed on methods having broad utility for the synthesis of fine chemicals.
Journal ArticleDOI
Practical Considerations in Kinetic Resolution Reactions
TL;DR: In this article, the authors provide a critical analysis of catalytic kinetic resolution reactions from a practical perspective, asking the question of when, if ever, is kinetic resolution the best option for the synthesis of an optically active target.
Journal ArticleDOI
Ligand-Accelerated Catalysis
TL;DR: In this article, a ligand-accelerated catalysis (LAC) was proposed to improve an existing catalyzed process by the addition of a specific ligand, which leads to a faster, faster reaction.
Related Papers (5)
The palladium-catalyzed oxidative kinetic resolution of secondary alcohols with molecular oxygen.
Eric M. Ferreira,Brian M. Stoltz +1 more