Journal ArticleDOI
Palladium complex catalyzed carbonylation of organic halides having β-hydrogens
Toshiaki Kobayashi,Masato Tanaka +1 more
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TLDR
In this paper, the first case of successful carbonylation of organic halides having β-hydrogens was reported, in which α-Pehnylethyl bromide, ethyl α-bromopropionate, and α-phenylpropylbromide were smoothly converted to the corresponding methyl ketones by treatment with carbon monoxide and palladium complex catalysts in the presence of tetramethyltin.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1981-02-10. It has received 23 citations till now. The article focuses on the topics: Carbonylation & Triphenylphosphine.read more
Citations
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Journal ArticleDOI
Progress in hydroformylation and carbonylation
TL;DR: The last 15 years of hydroformylation and carbonylation chemistry are reviewed in this article, including technical and commercial aspects, and the authors present a review of the most relevant papers.
Journal ArticleDOI
Palladium-katalysierte Kupplungsreaktionen organischer Elektrophile mit Organozinn-Verbindungen
TL;DR: Palladium-katalysierte Kupplungsreaktionen von Organozinn-Verbindungen with unterschiedlichsten organischen Elektrophilen sind eine relativ neue Methode zur Knupfung von Kohlenstoff-Kohlenstoffs-Bindungen.
Book ChapterDOI
Radicals in transition metal catalyzed reactions? transition metal catalyzed radical reactions?: a fruitful interplay anyway: part 3: catalysis by group 10 and 11 elements and bimetallic catalysis.
TL;DR: This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry and focuses on radical-based methods catalyzed by group 10 and group 11 metal complexes.
Book ChapterDOI
Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? – A Fruitful Interplay Anyway
TL;DR: This review summarizes the current status of radical-based transition metal catalyzed reactions in organic chemistry and covers catalytic radical reactions involving group 4 to group 7 elements.
Journal ArticleDOI
Palladium-catalyzed carbonylative cross-coupling reaction of 1-halo-1-alkenes with 9-alkyl-9-BBN derivatives. A direct synthesis of α,β-unsaturated ketones
TL;DR: In this article, the synthesis of α,β-unsaturated ketones by means of the palladium-catalyzed cross-coupling reaction between 9-alkyl-9-borabicyclo[3.3.1]nonanes (9-R-9BBN) and 1-halo-1-alkenes under carbon monoxide atmosphere is described.
References
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Journal ArticleDOI
Gas-phase reactions of organic anions as studied by the flowing afterglow technique
Journal ArticleDOI
Palladium-catalyzed carboalkoxylation of aryl, benzyl, and vinylic halides
Journal ArticleDOI
Palladium-catalyzed formylation of aryl, heterocyclic, and vinylic halides
A. Schoenberg,R. F. Heck +1 more
TL;DR: The Bromide (I) werden in Gegenwart von Tri-n-butyl- oder Triathylamin and dem Pd-Komplex (II) with einem CO-H2-Gemisch bei 80 bis 150°C uber die sich wahrscheinlich zunachst bildenden Organo-Pd-Verbindungen zu den Aldehyden (III) formyliert as mentioned in this paper.
Journal ArticleDOI
Carboalkoxylation of aryl and benzyl halides catalyzed by dichlorobis(triphenylphosphine)palladium(II)
John K. Stille,Pui Kwan Wong +1 more
Journal ArticleDOI
Palladium-catalyzed formylation of aryl, heterocyclic, and vinylic halides
A. Schoenberg,R. F. Heck +1 more
TL;DR: The Bromide (I) werden in Gegenwart von Tri-n-butyl- oder Triathylamin and dem Pd-Komplex (II) with einem CO-H2-Gemisch bei 80 bis 150°C uber die sich wahrscheinlich zunachst bildenden Organo-Pd-Verbindungen zu den Aldehyden (III) formyliert as mentioned in this paper.