Journal ArticleDOI
Pd(II) and Pt(II) Complexes of 1,2-Bis(pyridin-2-yl)ethane-N,N'
A. McFarlane,J. R. Lusty,Juan J. Fiol,Angel Terrón,Elies Molins,Carles Miravitlles,Virtudes Moreno +6 more
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In this paper, X-ray crystal structures and properties of the two Pd(II) and Pt(2) complexes [bpeH 2 ][PdCl 4 ] and [Pt(hpe)Cl 2 ] are described and correlated with the IR and 1 H NMR/13 C NMR spectroscopic data.Abstract:
X-ray crystal structures and properties of the two Pd(II) and Pt(II) complexes [bpeH 2 ][PdCl 4 ] and [Pt(hpe)Cl 2 ], [bpe=1,2-his(pyridin-2-yl)ethane] are described and correlated with the IR and 1 H NMR/ 13 C NMR spectroscopic data. In the case of the Pt(II) complex, the 1,2-bis(pyidin-2-yl)ethane is hound to the metal by the heterocycle nitrogen atoms hut no direct bond is found in the case of the Pd(II) complex. The ligand exhibits low energy geometries in both compounds: the cis-conformation in the Pt(II) complex, and the trans-conformation in the Pd(II) complexread more
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Structural Aspect of Platinum Coordination Compounds: Part II. Monomeric Pt11 Compounds with PtA3B and PtA2B2 Composition
Clive E. Holloway,Milan Melnik +1 more
TL;DR: In this article, the authors propose a method to solve the problem of unstructured data in the form of a set of sub-structured graphs, where each node represents a subspace.
Journal ArticleDOI
The Chemistry of [PtMe2(1,2-bis(2-pyridyl)ethane)]: Remarkable Impact of an Easily Dissociated Chelate Ligand
TL;DR: In this article, a new class of octahedral organoplatinum(IV) double cubane clusters was obtained on oxidation of complex 1 either with bromine or iodine, X2, and X = I, giving the first example of metalation of a CH2 group of the bpe ligand.
Journal ArticleDOI
Linear Bidentate Ligands (L) with Two Terminal Pyridyl N-Donor Groups Forming Pt(II)LCl2 Complexes with Rare Eight-Membered Chelate Rings.
TL;DR: NMR and X-ray diffraction studies were conducted on Pt(II)LCl2 complexes prepared with the new N-donor ligands N(SO2R)Me ndpa, providing rare examples of association-dissociation equilibria of N,N bidentate ligands in Pt( II) chemistry.