Journal ArticleDOI
Phosphomolybdate clusters as molecular building blocks in the design of one-, two- and three-dimensional organic–inorganic hybrid materials
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In this article, a modified strategy in which polyoxometalate clusters are linked through organic subunits to give an anionic hybrid substructure which may be further modified through the introduction of secondary metal-ligand complex (SMLC) cations, serving as a third component building block.About:
This article is published in Journal of Solid State Chemistry.The article was published on 2005-08-01. It has received 34 citations till now. The article focuses on the topics: Polyoxometalate & Ligand.read more
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Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications
TL;DR: Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded as soluble oxide fragments which play a great role in various areas ranging from catalysis, medicine, electrochemistry, photochromism,5 to magnetism.
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A pcu-type metal-organic framework with spindle [Zn7(OH)8]6+ cluster as secondary building units.
TL;DR: The in situ solvothermal reaction of 9,10-dicyanoanthracene and ZnCl(2)/NaN(3) gave the complex, {[Zn(7)(OH)(8)(DTA)(3)].H(2)O}(n) (), which presents a pcu-type topological framework formed by DTA(2-) bridging unprecedented heptanuclear spindle.
Journal ArticleDOI
Controllable self-assembly of four new metal–organic frameworks based on different phosphomolybdate clusters by altering the molar ratio of H3PO4 and Na2MoO4
TL;DR: By adjusting the molar ratio of the reactants H3PO4 and Na2MoO4, four new metal-organic frameworks, namely, CoH(bix)4[PMoVI8VV4O40(VIVO)2] (1), (H2bix), 2(NaHP2Mo5O23)·2H2O (2), H2(bIX)4 [Cd(H 2O)4]2+ cations to build one-dimensional (1D) chains.
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From chain to network: design and analysis of novel organic-inorganic assemblies from organically functionalized zinc-substituted polyoxovanadates and zinc organoamine subunits.
TL;DR: The different coordination abilities and geometries of the bidentate organodiamine ligands used in the four-reaction systems play important roles in the formation of the final structures: from straight chains to sinuate chains, to helical chiral chains, and finally to a 2D layer with helices.
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Employing Zinc Clusters as SBUs To Construct (3,8) and (3,14)-Connected Coordination Networks: Structures, Topologies, and Luminescence
TL;DR: In this paper, two metal-organic frameworks (MOFs), [Zn2(OH)(cpia)(bipy)0.5]n (1) and {[Zn7(OH]2(HOMe)2(cpia)4(bib)]·5H2O}n (2) (bib = 1,4-bis(imidazol-1-yl)benzene, H3cpia = 5-(4-carboxyphenoxy)isophthalic acid, bipy =
References
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Chemistry of the elements
TL;DR: In this article, the origins of the elements, isotopes and atomic weights Chemical periodicity and the periodic table were discussed, including the following elements: Hydrogen Lithium, sodium, potassium, rubidium, caesium and francium Beryllium, magnesium, calcium, strontium, barium and radium Boron Aluminium, gallium, indium and thallium Carbon Silicon Germanium, tin and lead Nitrogen Phosphorus Arsenic, antimony and bismuth Oxygen Sulfur Selenium, tellurium
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Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks.
Mohamed Eddaoudi,David B. Moler,Hailian Li,Banglin Chen,Theresa M. Reineke,Michael O'Keeffe,Omar M. Yaghi +6 more
TL;DR: Consideration of the geometric and chemical attributes of the SBUs and linkers leads to prediction of the framework topology, and in turn to the design and synthesis of a new class of porous materials with robust structures and high porosity.
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Organic-Inorganic Hybrid Materials: From "Simple" Coordination Polymers to Organodiamine-Templated Molybdenum Oxides.
TL;DR: A blueprint for the design of oxide materials is provided by nature and members of the ever-expanding class of polymeric coordination complex cations, novel molybdenum oxide substructures, such as the one shown, may be prepared.
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Metallosupramolecular squares: from structure to function
TL;DR: Metallosupramolecular squares have been successfully evolved over the past years as versatile substitutes of the conventional organic macrocycles owing to the development of reliable synthetic protocols and abundant structural variability (metals and ligands) as discussed by the authors.