Journal ArticleDOI
Photoactivation of Ruthenium Olefin Metathesis Initiators
Amos Ben-Asuly,Amos Ben-Asuly,Anna Aharoni,Charles E. Diesendruck,Yuval Vidavsky,Israel Goldberg,Bernd F. Straub,N. Gabriel Lemcoff +7 more
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TLDR
In this paper, the UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro−trans-dichtloro photoisomerization.About:
This article is published in Organometallics.The article was published on 2009-07-24. It has received 109 citations till now. The article focuses on the topics: Ring-opening metathesis polymerisation & Acyclic diene metathesis.read more
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Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
TL;DR: A comprehensive survey of photo-CRP reactions can be found in this article, where a large number of methods are summarized and further classified into subcategories based on the specific reagents, catalysts, etc., involved.
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Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
TL;DR: This review provides a comprehensive survey of photocontrolled, living radical polymerizations (photo-CRPs), and a large number of methods are summarized and further classified into subcategories based on the specific reagents, catalysts, etc., involved.
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Seeing the Light: Advancing Materials Chemistry through Photopolymerization.
TL;DR: This work highlights the utility of light as an energy source for mediating photopolymerization, and presents some promising examples of systems which are advancing materials production through their exploitation of photochemistry.
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Artificial light-gated catalyst systems.
Ragnar S. Stoll,Stefan Hecht +1 more
TL;DR: This Review outlines the general concept of light-gated catalysis based on photocaged and also photoswitchable systems, and discusses relevant examples of the past and recent literature.
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Approaches to Sustainable and Continually Recyclable Cross-Linked Polymers
David J. Fortman,David J. Fortman,Jacob P. Brutman,Guilhem X. De Hoe,Rachel L. Snyder,William R. Dichtel,Marc A. Hillmyer +6 more
TL;DR: In this paper, the authors discuss many of these approaches, and highlight efforts to sustainably produce recyclable cross-linked polymers, and present their thoughts on future challenges that must be overcome to enable widespread, viable, and more sustainable and practical implementation of these materials, including the sustainable sourcing of f...
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Journal ArticleDOI
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
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Olefin Metathesis and Beyond
TL;DR: In this paper, the authors provide an overview of the development of catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups.
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The remarkable metal-catalysed olefin metathesis reaction
TL;DR: The full potential of olefin metathesis will be realized only when additional catalysts are discovered that are truly practical and afford exceptional selectivity for a significantly broader range of reactions.
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Stereoelectronic parameters associated with N-heterocyclic carbene (NHC) ligands: A quest for understanding
TL;DR: A comprehensive overview of the progress in this area can be found in this paper, where the N-heterocyclic carbene-based organometallic chemistry has drawn increasing attention to this class of ancillary ligands.