Journal ArticleDOI
Polyaniline: a new concept in conducting polymers
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TLDR
In this paper, the emeraldine oxidation state of polyaniline was converted from an insulator to a metal by treatment with 1M aqueous HCl to form the corresponding salt, emeraldines hydrochloride.About:
This article is published in Synthetic Metals.The article was published on 1987-02-01. It has received 1286 citations till now. The article focuses on the topics: Polyaniline & Conductive polymer.read more
Citations
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"Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture).
TL;DR: Herein is described a novel, simple, and cheap method to prepare patterns of conducting polymers by a process which the authors term, "Line Patterning".
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Polyaniline: a polymer with many interesting intrinsic redox states
TL;DR: The ability of aniline polymers to exist in a large number of intrinsic redox states makes them a unique and interesting class of polymeric materials as mentioned in this paper, and a number of fine reviews on the synthesis, physicochemical and electrochemical properties of the polymer have also appeared during this period.
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Conductive polymers: towards a smart biomaterial for tissue engineering.
TL;DR: Focusing mainly on polypyrrole, polyaniline and poly(3,4-ethylenedioxythiophene), this work reviews conductive polymers from the perspective of tissue engineering.
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Polyaniline: A historical survey
TL;DR: A survey of the literature available on conducting organic polyaniline can be found in this paper, where the authors provide a survey of some of the most recent work on polyanILine.
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Electrochemistry of Conducting Polymers—Persistent Models and New Concepts†
TL;DR: Electropolymerization in Novel Electrolytic Media 4745: Influence of the Polymerization Technique, Influence of Experimental Conditions, and Specific Phenomena of n-Doping.
References
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Journal ArticleDOI
‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime
J. C. Chiang,Alan G. MacDiarmid +1 more
TL;DR: The emeraldine base form of polyaniline, which consists of equal numbers of reduced and oxidized repeat units, is doped to the metallic conducting regime by aqueous 1 M HCl as mentioned in this paper.
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CCXLIII.—Aniline-black and allied compounds. Part I
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Electrochemical chains using protolytic organic semiconductors
TL;DR: The properties of organic semiconductors, especially polyanilines, are reviewed in this article in the light of recent work, and the properties of the polyaniliines are discussed in detail.
Journal ArticleDOI
Transport and Magnetic Resonance Studies of Polyaniline
Jean-Pierre Travers,J. A. Chroboczek,F. Devreux,F. Genoud,M. Nechtschein,Akheel Ahmed Syed,E.M. Genies,C. Tsintavis +7 more
TL;DR: In this article, the metal-insulator transition upon pH variation has been investigated in polyaniline samples equilibrated at different pH levels, and it has been shown that the metal insulator becomes metal-conductivity, thermoelectric power, spin concentration and spin dynamics changes with pH variation.
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Vibrational spectra of polyaniline and its 15N- and 2H-substituted derivatives in as-polymerized, alkali-treated and reduced states
TL;DR: In this article, the Raman spectra of polyaniline and its 15 N- and 2 H-substituted derivatives were studied in as-polymerized (conductive), alkali-treated (insulating) and electrochemically reduced (inulating) states.
Related Papers (5)
‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime
J. C. Chiang,Alan G. MacDiarmid +1 more