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Polyphenols in cocoa (Theobroma cacao L.)

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TLDR
A review of the latest developments and studies reported for cocoa polyphenols and its contribution in this area for the betterment of human health is provided in this paper, where the main classes of polyphenolic compounds identified are such as simple phenols, benzoquinones, phenolic acids, acetophenone, phenylacetic acids, hydroxycinnamic acids, phenylene glycols, phenylonic acid and phenylpropenes, coumarines, chromones, naphtoquinone, xanthones, stilbenes,
Abstract
Polyphenols have gained much interest recently due to its antioxidant capacity and possible benefits to human health such as anti-carcinogenic, anti-atherogenic, anti-ulcer, antithrombotic, anti-inflammatory, immune modulating, anti-microbial, vasodilatory and analgesic effects. Cocoa (Theobroma cacao L.) is a rich source of polyphenols and reported having high antioxidant activity than teas and red wines. Cocoa and its derived products (cocoa powder, cocoa liquor and chocolates) contain varied polyphenol contents and possess different levels of antioxidant potentials. The polyphenols in cocoa beans contribute to about 12-18% of the dry weight of the whole bean. Main classes of polyphenolic compounds identified are such as simple phenols, benzoquinones, phenolic acids, acetophenones, phenylacetic acids, hydroxycinnamic acids, phenylpropenes, coumarines, chromones, naphtoquinones, xanthones, stilbenes, anthraquinones, flavonoids, lignans and lignins. Three main groups of cocoa polyphenols can be distinguished namely the catechins (37%), anthocyanins (4%) and proanthocyanidins (58%). The main catechin is (-)-epicatechin with up to 35% of polyphenol content. Effects of processing could influence the polyphenols of cocoa and its products. The aim of this paper is to provide a review of some of the latest developments and studies reported for cocoa polyphenols and its contribution of this area for the betterment of human health.

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Status, supply chain and processing of cocoa - A review

TL;DR: In this paper, a review of the global status, market scenario and processing of the cocoa into different products has been outlined which may be helpful for the concerned communities, and the SWOT analysis has been carried out to identify the global strength, opportunities and threats.
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The Content of Polyphenolic Compounds in Cocoa Beans (Theobroma cacao L.), Depending on Variety, Growing Region, and Processing Operations: A Review

TL;DR: Thermal processing of cocoa beans and cocoa derivative products at relatively high temperatures may in addition to favorable physicochemical, microbiological, and organoleptic changes result in a decrease of polyphenols concentration.
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The effect of roasting on the phenolic compounds and antioxidant potential of baru nuts [Dipteryx alata Vog.]

TL;DR: The effect of roasting on phenolic compounds and antioxidant activities in baru nuts ( Dipteryx alata Vog) with and without peels were investigated in this paper, which showed that approximately 50% of the total phenolic content (Folin Ciocalteu assay) and 90% of free radical-scavenging activity (DPPH) were present in the peel of the baru nut.
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Valorization of cacao pod husk through supercritical fluid extraction of phenolic compounds

TL;DR: In this paper, a Box-Behnken design was employed to optimize the SC-CO 2 for the development of suitable and green process focused on obtaining an extract enriched in phenolic compounds from this byproduct, considering temperature, pressure and co-solvent (ethanol) as factors.
References
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The Chemistry behind Antioxidant Capacity Assays

TL;DR: This analysis suggests that the total phenols assay by FCR be used to quantify an antioxidant's reducing capacity and the ORAC assay to quantify peroxyl radical scavenging capacity, to comprehensively study different aspects of antioxidants.
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Polyphenols: Chemistry, Dietary Sources, Metabolism, and Nutritional Significance

TL;DR: An overview of the nutritional effects of the main groups of polyphenolic compounds, including their metabolism, effects on nutrient bioavailability, and antioxidant activity, is offered, as well as a brief description of the chemistry ofpolyphenols and their occurrence in plant foods.
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Polyphenols: antioxidants and beyond

TL;DR: This supplemental issue of The American Journal of Clinical Nutrition offers an overview of the experimental, clinical, and epidemiologic evidence of the effects of polyphenols on health.
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Cocoa Has More Phenolic Phytochemicals and a Higher Antioxidant Capacity than Teas and Red Wine

TL;DR: Cocoa exhibited the highest antioxidant activity among the samples in ABTS and DPPH assays, with VCEACs of 1128 and 836 mg/serving, respectively, suggesting that cocoa is more beneficial to health than teas and red wine in terms of its higher antioxidant capacity.
Journal ArticleDOI

Review on polyphenols in Theobroma cacao: changes in composition during the manufacture of chocolate and methodology for identification and quantification

TL;DR: In this article, a review of the literature on the available methodology for analysis, quantification, isolation, purification, and structure elucidation of polyphenols in cocoa components and other commodities is presented.
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