Journal ArticleDOI
Preparation, characterization and electrochemical studies of 1,1′-bis(diphenylphosphino) ferrocene (dppf) derivatives. Crystal structure of [dppfCo(NO)2][SbF6]
Annelise Engel Gerbase,Eduardo J. S. Vichi,Edison Stein,Livio Amaral,Adalberto Vasquez,Manfredo Hörner,Cäcilia Maichle-Mössmer +6 more
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TLDR
In this article, the neutral dppfFe(NO)2 (1), the novel cationic [dppfCo(NO), SbF6] (2), as well as the dppfeFe(CO), 1,1′-bis-(diphenylphosphino)ferrocene) complexes were prepared and characterized.About:
This article is published in Inorganica Chimica Acta.The article was published on 1997-12-01. It has received 20 citations till now. The article focuses on the topics: 1,1'-Bis(diphenylphosphino)ferrocene & Crystal structure.read more
Citations
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Journal ArticleDOI
Coordination and organometallic chemistry of metal-NO complexes.
Journal ArticleDOI
Ligating ability of 1,1′-bis(diphenylphosphino)ferrocene: a structural survey (1994–1998)
TL;DR: In this article, the ligating ability of 1,1′-bis(diphenylphosphino) ferrocene is discussed. But the focus is on the extensive coordination chemistry exhibited by this ligand to transition metals.
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Group 10 metal compounds of 1,1′-bis(diphenylphosphino)ferrocene (dppf) and 1,1′-bis(diphenylphosphino)ruthenocene: a structural and electrochemical investigation. X-ray structures of [MCl2(dppr)] (M=Ni, Pd)
Chip Nataro,Alison N. Campbell,Michelle A. Ferguson,Christopher D. Incarvito,Arnold L. Rheingold +4 more
TL;DR: In this paper, the binding of 1,1′-bis(diphenylphosphino)ferrocene (dppf) and 1, 1′-bi-bis (diphexylphophosphino)-ruthenocene (dplr) to Group 10 metals was investigated at various temperatures and concentrations.
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Synthesis, characterization, X-ray structure and preliminary in vitro antitumor activity of the nitrosyl complex fac-[RuCl3(NO)(dppf)], dppf = 1,1′-bis(diphenylphosphine)ferrocene
Gustavo Von Poelhsitz,André L. Bogado,Márcio P. de Araujo,Heloisa S. Selistre-de-Araujo,Javier Ellena,Eduardo E. Castellano,Alzir A. Batista +6 more
TL;DR: The reaction of RuCl3NO with stoichiometric amount of dppf, 1,1′-bis(diphenylphosphino)ferrocene, afforded the new neutral nitrosyl complex fac-[RuCl3(NO)(dppf)] which was characterized by spectroscopical, electrochemical and X-ray crystallography techniques as well as elemental analysis.
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A structure-based analysis of the vibrational spectra of nitrosyl ligands in transition-metal coordination complexes and clusters.
TL;DR: The vibrational spectra of nitrogen monoxide or nitric oxide (NO) bonded to one or to several transition-metal (M) atom(s) in coordination and cluster compounds are analyzed in relation to the various types of such structures identified by diffraction methods.
References
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An empirical method for correcting diffractometer data for absorption effects
N. Walker,David I. Stuart +1 more
TL;DR: In this article, a Fourier series in the polar angles of the incident and diffracted beam paths is used to model an absorption surface for the difference between the observed and calculated structure factors.
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Mössbauer Spectroscopy
TL;DR: The Mössbauer Effect Methodology as mentioned in this paper is a well-known method for nuclear power analysis and it has been used extensively in the nuclear power research community, e.g., in the first Symposium.
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Principles of structure, bonding, and reactivity for metal nitrosyl complexes
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.DELTA.R-ring contributions to phosphorus-31 NMR parameters of transition-metal-phosphorus chelate complexes
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Cyclic Voltammetry—“Electrochemical Spectroscopy”. New Analytical Methods (25)
TL;DR: The cyclic voltammetry has the further attraction of providing information not only on the thermodynamics of redox processes but also on the kinetics of heterogeneous electron-transfer reactions and coupled chemical reactions as discussed by the authors.