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Journal ArticleDOI

Principles of structure, bonding, and reactivity for metal nitrosyl complexes

John H. Enemark, +1 more
- 01 Sep 1974 - 
- Vol. 13, Iss: 4, pp 339-406
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This article is published in Coordination Chemistry Reviews.The article was published on 1974-09-01. It has received 1436 citations till now. The article focuses on the topics: Reactivity (chemistry).

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Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

TL;DR: Functionalization via covalent grafting of organic functions allows to tune the redox and acid-base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity.
Journal ArticleDOI

Surface chemistry of porphyrins and phthalocyanines

TL;DR: The surface chemistry of porphyrins, phthalocyanines, their metal complexes, and related compounds, with particular focus on chemical reactions at solid/vacuum interfaces, is discussed in this paper.
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Non-innocent ligands in bioinorganic chemistry—An overview

TL;DR: In this paper, the most common instances where non-innocent behaviour of redox-active ligands, either substrates or supporting components, is observed in a biochemical context are discussed.
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Nature of active species in copper-based catalysts and their chemistry of transformation of nitrogen oxides

TL;DR: Copper-based catalysts are active in a wide range reactions of transformation of nitrogen oxides and represent an useful model system to better understand the fundamental aspects of the chemistry and mechanism of reaction of catalytic transformation of these pollutants.
References
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Stereochemistry of hemes and other metalloporphyrins.

TL;DR: Metalloporphyrins, most notably the iron porphyrin, observe clearly defined, internally consistent, structural principles that promise to be fully applicable to the hemes in the several families of the hemoproteins.
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