Journal ArticleDOI
Pyrolysis of garlic husk biomass: Physico-chemical characterization, thermodynamic and kinetic analyses
TLDR
In this paper, non-isothermal thermogravimetric experiments pertaining to garlic husk (GH) biomass were carried out at four heating rates, namely, 5, 10, 15 and 20°C/min.About:
This article is published in Bioresource Technology Reports.The article was published on 2020-12-01. It has received 50 citations till now.read more
Citations
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Co-pyrolysis of petroleum coke and banana leaves biomass: Kinetics, reaction mechanism, and thermodynamic analysis.
Kamal Gupta,Rajnish Kumar Singh,Trilok Patil,Deeksha Pandey,Shyam P. Tekade,Ashish N. Sawarkar +5 more
TL;DR: In this article, a comprehensive kinetics and thermodynamic investigation of co-pyrolysis of petroleum coke (PC) and banana leaves biomass (BLB) is presented.
Journal ArticleDOI
Co-pyrolysis of petroleum coke and banana leaves biomass: Kinetics, reaction mechanism, and thermodynamic analysis
TL;DR: In this paper , a comprehensive kinetics and thermodynamic investigation of co-pyrolysis of petroleum coke (PC) and banana leaves biomass (BLB) is presented.
Journal ArticleDOI
Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis
TL;DR: The master plots method is usually used to determine the kinetic mechanism function once the activation energies as a function of conversion are estimated from an isoconversional method as discussed by the authors. But the accuracy of the resulting kinetic mechanism functions is strongly dependent on the variation degree of the frequency factor with conversion and the conversion dependency of activation energy.
Journal ArticleDOI
Insights into kinetics, reaction mechanism, and thermodynamic analysis of pyrolysis of rice straw from rice bowl of India
TL;DR: In this article, various aspects of pyrolysis of rice straw (RS) from rice bowl of India including thermal degradation, kinetics, reaction mechanism, and thermodynamic parameters have been deliberated based on thermogravimetric experiments conducted at different heating rates, such as, 5, 10, 15, and 20°C/min in N2 environment.
Journal ArticleDOI
Pyrolysis of agricultural crop residues: An overview of researches by Indian scientific community
TL;DR: In this article, an overview of reported investigations by Indian researchers pertaining to pyrolysis of agro-residues along with issues and possible solutions have been presented, in terms of proximate, ultimate, biochemical composition, and higher heating values.
References
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Journal ArticleDOI
A New Method of Analyzing Thermogravimetric Data
TL;DR: In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.
Journal ArticleDOI
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data
Sergey Vyazovkin,Alan K. Burnham,José M. Criado,Luis A. Pérez-Maqueda,Crisan Popescu,Nicolas Sbirrazzuoli +5 more
TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
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Variation of Peak Temperature With Heating Rate in Differential Thermal Analysis
TL;DR: In this article, the temperature at which the maximum deflection is observed varies with heating rate for certain types of reactions, and an expression can be derived relating this variation with the kinetics of the reaction.
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The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods
TL;DR: In this article, a classification of model-free isoconversion methods for the calculation of activation energies of thermally activated reactions is proposed, by deriving expressions for the main sources of error which includes the inaccuracy in reaction rate measurement, approximations for the temperature integral and inaccuracies in determination of temperature for equivalent fraction transformed.
Journal ArticleDOI
Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies
TL;DR: A critical review of kinetic models and mathematical approximations currently employed in solid state thermal analysis is provided and analysis of thermal decomposition data obtained from two agricultural residues, nutshells and sugarcane bagasse reveals the inherent difficulty and risks involved in modeling heterogeneous reaction systems.