Rare earth elements: critical resources for high technology

Abstract: The rare earth elements (REE) form the largest chemically coherent group in the periodic table. Though generally unfamiliar, the REE are essential for many hundreds of applications. The versatility and specificity of the REE has given them a level of technological, environmental, and economic importance considerably greater than might be expected from their relative obscurity. The United States once was largely self-sufficient in these critical materials, but over the past decade has become dependent upon imports (fig. 1). In 1999 and 2000, more than 90% of REE required by U.S. industry came from deposits in China. Although the 15 naturally occurring REE (table 1; fig. 2) are generally similar in their geochemical properties, their individual abundances in the Earth are by no means equal. In the continental crust and its REE ore deposits, concentrations of the most and least abundant REE typically differ by two to five orders of magnitude (fig. 3). As technological applications of REE have multiplied over the past several decades, demand for several of the less abundant (and formerly quite obscure) REE has increased dramatically. The diverse nuclear, metallurgical, chemical, catalytic, electrical, magnetic, and optical properties of the REE have led to an ever increasing variety of applications. These uses range from mundane (lighter flints, glass polishing) to high-tech (phosphors, lasers, magnets, batteries, magnetic refrigeration) to futuristic (hightemperature superconductivity, safe storage and transport of hydrogen for a post-hydrocarbon economy).