Journal ArticleDOI
Reactions of oxomolybdenum(IV) complexes with halogens and hydrogen halides
Reads0
Chats0
About:
This article is published in Inorganic and Nuclear Chemistry Letters.The article was published on 1975-09-01. It has received 13 citations till now. The article focuses on the topics: Halogen.read more
Citations
More filters
Book ChapterDOI
1, 1-Dithiolato Complexes of the Transition Elements
TL;DR: The 1,2-dithio ligands with the Group I transition metals have been extensively reviewed by Coucouvanis as mentioned in this paper, who stressed the versatility of these ligands and the academic and industrial importance of their metal complexes.
Journal ArticleDOI
Synthesis, Spectroscopic Characterization, and Structural Studies of Bis(m-sulfido)bis[{O,O-dialkyl (alkylene) dithiophosphato}oxomolybdenum(V)] Complexes. Crystal Structures of Mo(2)O(2)S(2)[S(2)P(OEt)(2)](2), Mo(2)O(2)S(2)[S(2)P(OEt)(2)](2).2NC(5)H(5), and Mo(2)O(3)[S(2)P(OPh)(2)](4).
TL;DR: In this article, a series of new complexes, Mo2O2S2[S2P(OR)2]2 (where R = Et, n-Pr, i-Pr) were obtained by dropwise addition of an ethanolic solution of the ammonium or sodium salt of the appropriate O,O-dialkyl or -alkylene dithiophosphoric acid, or the acid itself, to a hot aqueous solution of molybdenum(V) pentachloride.
Journal ArticleDOI
Studies on the reactivity of oxodihalobis(diethyldithiocarbamato) molybdenum(VI) and tungsten(VI) complexes
TL;DR: The complexes OMoX 2 L 2 (L = S 2 )CNEt 2 ) 2 and OMoXL 2 (X = Cl, Br) as mentioned in this paper showed the lack of atom transfer ability of tungsten(VI) relative to its molybdenum analog.
References
More filters
Journal ArticleDOI
Preparation and characterization of two series of dimeric molybdenum(V) N,N-dialkyldithiocarbamates. Their interrelation and chemistry as a model for the active site of nitrogenase
Journal ArticleDOI
Reactions of oxobis(N,N-dialkyldithiocarbamato) molybdenum(IV) with unsaturated organic molecules and their biochemical implications
Journal ArticleDOI
Chemical evolution of a nitrogenase model. VII. Reduction of nitrogen
TL;DR: The current molybdothiol model systems were expanded to include ferredoxin-type complexes as electron-transfer catalysts, which provided new catalytically active systems containing molybdenum, iron, labile sulfide, and RSH components in proportions similarmore to that observed in native nitrogenase.
Related Papers (5)
Synthesis of molybdenum(IV) and molybdenum(V) complexes using oxo abstraction by phosphines. Mechanistic implications
Dialkyldithiocarbamate complexes of molybdenum(V) and molybdenum(VI)
Fred W. Moore,Melvin L. Larson +1 more