Journal ArticleDOI
Room-Temperature AuI-Catalyzed CC Bond Formation through a Tandem Friedel–Crafts-Type Addition/Carbocyclization Reaction†
Reads0
Chats0
About:
This article is published in Angewandte Chemie.The article was published on 2006-11-13. It has received 147 citations till now. The article focuses on the topics: Friedel–Crafts reaction & Cascade reaction.read more
Citations
More filters
Journal ArticleDOI
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
Journal ArticleDOI
Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
Alois Fürstner,Paul W. Davies +1 more
TL;DR: The ability of platinum and gold catalysts to effect powerful atom-economic transformations has led to a marked increase in their utilization and the application of platinum- and gold-catalyzed transformations in natural product synthesis is discussed.
Journal ArticleDOI
Ligand effects in homogeneous Au catalysis.
TL;DR: The ways in which selectivity can be controlled in homogeneous Au catalysis are enumerated, in the hope that lessons to guide catalyst selection and the design of new catalysts may be distilled from a thorough evaluation of ligand, counterion, and oxidation state effects as they influence chemo-, regio-, and stereoselectivity in homogeneity AuCatalysis.
Journal ArticleDOI
Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective.
TL;DR: The proposed involvement of cyclopropyl metal carbenes of type 4 in the electrophilic activation of enynes by transition metals was first substantiated in reactions catalyzed by Pd(II), in which the initially formed cycloprostyl palladiumCarbenes undergo [4 + 2] cycloaddition with the double bond of the conjugate enyne.
Journal ArticleDOI
Gold-catalyzed organic transformations.
Zigang Li,Chad Brouwer,Chuan He +2 more
TL;DR: Thanks to gold-based catalysts, various organic transformations have been accessible under facile conditions with both high yields and chemoselectivity.
References
More filters
Journal ArticleDOI
The atom economy--a search for synthetic efficiency
TL;DR: Transition metal-catalyzed methods that are both selective and economical for formation of cyclic structures, of great interest for biological purposes, represent an important starting point for this long-term goal.
Journal ArticleDOI
Origins, Current Status, and Future Challenges of Green Chemistry†
TL;DR: The origins and basis of green chemistry chart a course for achieving environmental and economic prosperity inherent in a sustainable world.
Book
Principles and applications of organotransition metal chemistry
TL;DR: A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
Journal ArticleDOI
Ru-, Rh-, and Pd-Catalyzed C-C Bond Formation Involving C-H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects
Journal ArticleDOI
Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution
TL;DR: The Holy Grail of C-H activation research is not to find new CH activation reactions but to obtain an understanding of them that will allow the development of reagents capable of selective transformations of C -H bonds into more reactive functionalized molecules as discussed by the authors.
Related Papers (5)
Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
Alois Fürstner,Paul W. Davies +1 more