Journal ArticleDOI
Shock tube determination of the rate coefficient for the reaction N2+O→NO+N
Jamie P. Monat,Ronald K. Hanson,Charles H. Kruger +2 more
- Vol. 17, Iss: 1, pp 543-552
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In this paper, the rate coefficient for the reaction N 2 + O → k 1 NO + N has been measured in the temperature range 2384-3850 K using a shock tube technique.Abstract:
The rate coefficient for the reaction N 2 + O → k 1 NO + N has been measured in the temperature range 2384–3850 K using a shock tube technique. Test gas mixtures consisting of N2, O2, N2O and Kr were heated by incident shock waves, and the concentration of NO in the post-shock region was monitored using two independent spectroscopic techniques: IR emission at 5.3 μm, and absorption of CO laser radiation at 5.17 μm. The two methods yielded excellent agreement. The importance of interferences from other reactions was minimized by careful tailoring of the test mixture composition, in particular by using N2O rather than O2 as a source of 0 atoms. The rate coefficient k1 was determined by comparing experimental and calculated NO profiles using a computer simulation in which k1 was an adjustable parameter. The results of 20 experiments indicate that k1=1.84×1014 exp (−76,250/RT) cm3/mol×s with an uncertainty of approximately ±35% in the temperature range investigated.read more
Citations
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Journal ArticleDOI
Modeling nitrogen chemistry in combustion
TL;DR: In this paper, a review of the current understanding of the mechanisms that are responsible for combustion-generated nitrogen-containing air pollutants is discussed, along with the chemistry of NO removal processes such as reburning and selective non-catalytic reduction of NO.
Journal ArticleDOI
Assessment of two-temperature kinetic model for ionizing air
TL;DR: In this paper, a two-temperatur e chemical-kinet ic model for air is assessed by comparing theoretical results with existing experimental data obtained in shock tubes, ballistic ranges, and flight experiments.
Journal ArticleDOI
Components, formulations, solutions, evaluation, and application of comprehensive combustion models
TL;DR: In this paper, a review of the state-of-the-art of the various components or submodels that are required in a comprehensive combustion model is presented, and representative applications of comprehensive combustion models are summarized, and three sets of model simulations are compared with experimental data.
Journal ArticleDOI
Thermal rate constants of the N 2 +O→NO+N reaction using ab initio 3 A″ and 3 A' potential energy surfaces
Deepak Bose,Graham V. Candler +1 more
TL;DR: In this article, an analytical fit of the lowest 3A′ potential energy surface of the N2+O→NO+N reaction based on the CCI ab initio data is obtained.
Proceedings ArticleDOI
A review of reaction rates in high temperature air
TL;DR: In this article, the rate coefficients for the chemical reactions in nonequilibrium high temperature air are reviewed and collated, and a selected set of such values is recommended for use in hypersonic flow calculations.
References
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Journal ArticleDOI
Temperature dependence of O(1D) rate constants for reactions with O2, N2, CO2, O3, and H2O
TL;DR: In this article, the absolute rate constants and their temperature dependencies for the deactivation of O(1D) by five important atmospheric gases are reported and compared with other energy dependent measurements and with the theories reported in the literature.
Journal ArticleDOI
Shock‐Tube Study of the Kinetics of Nitric Oxide at High Temperatures
Kurt L. Wray,J. Derek Teare +1 more
TL;DR: In this article, the absorption coefficients of the species NO, O2, and N2 as functions of the respective vibrational temperatures were determined by measuring the absorption by the shock-heated gas at a point in the time history corresponding to complete vibrational relaxation but before the onset of dissociation.
Journal ArticleDOI
O2 Dissociation Rates O2‐Ar Mixtures
Morton Camac,Arthur Vaughan +1 more
TL;DR: In this paper, the authors measured the O2 dissociation rate in shock-heated oxygen-argon mixtures with the ultraviolet light absorption technique described in the preceding article, and compared the results with those of Byron and Matthews.
Journal ArticleDOI
Single‐Pulse Shock Tube Studies of the Kinetics of the Reaction N2+O2⇄2NO between 2000–3000°K
TL;DR: The single temperature pulse technique has been used to study the kinetics of the formation of nitric oxide in the temperature range from 2000° to 3000°K, and it has been found that the reaction are consistent with the chain mechanism proposed by Zeldovich.
Journal ArticleDOI
Investigation of Nitric Oxide Formation Kinetics in Combustion Processes: The Hydrogen-Oxygen-Nitrogen Reaction
TL;DR: In this paper, an experimental and analytical investigation of the kinetics of formation of NO in shock-induced combustion of hydrogen-oxygen-nitrogen mixtures has been carried out.