Journal ArticleDOI
Silylene complexes stabilized by sulphur substituents; a structure and reactivity study
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TLDR
A base-stabilized silylene (silanediyl) complex (t-BuS)2(HMPA)Si Fe(CO)4 (9b) has been prepared from Na2Fe(CO), 4 and (tBuS), 2SiCl2 (2b) in the presence of HMPA (hexamethylphosphoric triamide).About:
This article is published in Polyhedron.The article was published on 1991-01-01. It has received 31 citations till now. The article focuses on the topics: Silylene & Nuclear magnetic resonance spectroscopy.read more
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Journal ArticleDOI
Reactivity of silylene complexes
TL;DR: The metal-silicon double bond in silylene complexes is highly polarized in a Mδ−−Siδ+ manner as discussed by the authors, and silyl(silylene) complexes exhibit high reactivities toward nucleophiles, such as water, alcohols, ketones, isocyanates, and phosphorus ylides.
Journal ArticleDOI
Transition metal complexes of silylenes, silenes, disilenes, and related species
Journal ArticleDOI
Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5-C5Me5)(Me3P)2RuSiX2]+ (X = Thiolate, Me, and Ph)
TL;DR: In this article, the triflate group of ruthenium silyl complexes of the type Cp*(Me3P)2RuSiR3 (Cp* = η5-C5Me5; SiR3 = SiCl3 (1), Si(NMe2)3, Si(SEt)3 (3), si(S-2-Naph)3), (4), (5),Si(SCy)2Cl (6), and Si(SMes)2CL (7, Mes = 2
Book ChapterDOI
Transition‐Metal Silyl Complexes
TL;DR: A general introduction to Late-Transition-Metal Silicon-Containing Complexes is given in this article, where the authors describe the following groups of Silyl Complexes:
Journal ArticleDOI
Bimetallic silicon chemistry: New opportunities in coordination and organometallic chemistry
TL;DR: In this article, the authors present a review of the properties of the bridging -Si(OR)3 ligand in heterobimetallic complexes and present several reactions that are directly relevant to the mechanisms of currently investigated catalytic systems.
References
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Journal ArticleDOI
Coherent X‐Ray Scattering for the Hydrogen Atom in the Hydrogen Molecule
TL;DR: In this paper, the x-ray form factors for a bonded hydrogen in the hydrogen molecule have been calculated for a spherical approximation to the bonded atom, and the corresponding complex scattering factors have also been calculated.
Journal ArticleDOI
Scattering factors computed from relativistic Dirac–Slater wave functions
D. T. Cromer,J. T. Waber +1 more
Book ChapterDOI
Calculation of Molecular Structure and Energy by Force-Field Methods
TL;DR: In this paper, the authors discuss the calculation approaches to determine molecular structure and energy by force-field methods, including the ab initio method, the force field method, mechanical model, and energy minimization schemes.
Journal ArticleDOI
Chemistry of organosilicon compounds
TL;DR: In this paper, two 1,2-disilacyclobutenes were prepared by the reaction of tetramethyldisilene with acetylenes, and several reactions of these new 1 2 disilacy clobutenets including oxidation, silylene insertion, iron carbonyl insertion, and addition to acetylene and dienes are reported.
Journal ArticleDOI
Identification of some intermediates in the titanocene-catalyzed dehydrogenative coupling of primary organosilanes
TL;DR: In this paper, le dimere de Cp 2 TiSiH 2 C 6 H 5 (Cp=cyclopentadienyl), the dimerisation ayant lieu par l'intermediaire d'une paire de ponts Ti−H−Si.