Journal ArticleDOI
Simple Syntheses of Aryl Alkyl Thioethers and of Aromatic Thiols from Unactivated Aryl Halides and Efficient Methods for Selective Dealkylation of Aryl Alkyl Ethers and Thioethers
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This article is published in Synthesis.The article was published on 1983-01-01. It has received 99 citations till now. The article focuses on the topics: Aryl & Ether.read more
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Coulomb blockade and the Kondo effect in single-atom transistors
Jiwoong Park,Jiwoong Park,Abhay Pasupathy,Jonas I. Goldsmith,Connie Chang,Yuval Yaish,Jason R. Petta,Marie Rinkoski,James P. Sethna,Héctor D. Abruña,Paul L. McEuen,Daniel C. Ralph +11 more
TL;DR: Two related molecules containing a Co ion bonded to polypyridyl ligands, attached to insulating tethers of different lengths are examined, enabling the fabrication of devices that exhibit either single-electron phenomena, such as Coulomb blockade or the Kondo effect.
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Copper in cross-coupling reactions: The post-Ullmann chemistry
TL;DR: A number of methods using various copper complexes and salts to carry out cross-coupling reactions leading to the formation of C heteroatom (C N, C O, C S, C P, C Se), C C, and C metal bonds have been proposed as discussed by the authors.
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Pd2(dba)3/Xantphos-catalyzed cross-coupling of thiols and aryl bromides/triflates
TL;DR: In this article, the cross-coupling of aliphatic and aromatic thiols and aryl bromides/triflates mediated by a Pd2(dba)3/Xantphos catalytic system in refluxing xylene (140°C) affords the corresponding thioethers in good yield.
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Thioether Side Chains Improve the Stability, Fluorescence, and Metal Uptake of a Metal–Organic Framework
Jun He,Ka-Kit Yee,Zhengtao Xu,Matthias Zeller,Allen D. Hunter,Stephen Sin-Yin Chui,Chi-Ming Che +6 more
TL;DR: In this article, the carboxyl-thioether combination was used for functionalizing metal-organic frameworks (MOFs) in connection with the prototypic MOF-5 system, where the thioether side chain was placed at the 2,5 positions of bdc, and the resultant molecule (L) was crystallized with Zn(II) ions into a porous, cubic network.
Journal ArticleDOI
A persulfurated benzene molecule exhibits outstanding phosphorescence in rigid environments: from computational study to organic nanocrystals and OLED applications
Giacomo Bergamini,Andrea Fermi,Andrea Fermi,Chiara Botta,Umberto Giovanella,Simone Di Motta,Fabrizia Negri,Romain Peresutti,Romain Peresutti,Marc Gingras,Marc Gingras,Paola Ceroni +11 more
TL;DR: In this article, a hexathio-benzene core and peripheral tolyl substituents exhibits outstanding phosphorescence properties in some environments favoring rigidity, in the solid state and in a solid matrix at 77 K, while no luminescence is recorded in solution at room temperature.