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Journal ArticleDOI

Size effects on dissociation rates of polycyclic aromatic hydrocarbon cations : laboratory studies and astrophysical implications

H. W. Jochims, +4 more
- 01 Jan 1994 - 
- Vol. 420, Iss: 1, pp 307-317
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This article is published in The Astrophysical Journal.The article was published on 1994-01-01. It has received 212 citations till now. The article focuses on the topics: Astrochemistry & Dissociation (chemistry).

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Journal ArticleDOI

Interstellar Polycyclic Aromatic Hydrocarbon Molecules

TL;DR: In this paper, a review of the observed mid-IR spectral properties of polycyclic aromatic hydrocarbons (PAHs) is presented, emphasizing the contribution of these species to photoelectric heating and the ionization balance of the interstellar gas and to the formation of small hydrocarbon radicals and carbon chains.
Journal ArticleDOI

Infrared Emission from Interstellar Dust. II. The Diffuse Interstellar Medium

TL;DR: In this article, the authors present a quantitative model for the infrared emission from dust in the diffuse interstellar medium, which consists of a mixture of amorphous silicate grains and carbonaceous grains, each with a wide size distribution ranging from molecules containing tens of atoms to large grains 1 μm in diameter.
Journal ArticleDOI

The molecular universe

TL;DR: In this paper, a review of molecular observations in various spectral windows and summarizes the chemical and physical processes involved in the formation and evolution of interstellar molecules is presented, focusing on the characteristics of complex polycyclic aromatic hydrocarbon molecules and fullerenes.
Journal ArticleDOI

Gas-phase infrared multiple photon dissociation spectroscopy of mass-selected molecular ions

TL;DR: In this paper, the authors present an overview of recent work on the infrared spectroscopy of mass-selected gas-phase molecular ions, where the ions are stored and isolated in a quadrupole ion trap where they are investigated with infrared multiple photon dissociation using a free electron laser (FEL).
Journal ArticleDOI

The evolution of amorphous hydrocarbons in the ISM: dust modelling from a new vantage point

TL;DR: In this paper, a power-law distribution of small a-C grains and log-normal distributions of large a-SilFe and aC(:H) grains are used to explore dust evolution in the interstellar medium, and it is shown that mantle accretion in molecular clouds and UV photo-processing in photodominated regions are likely the major drivers of dust evolution.
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