Journal ArticleDOI
Spectral evidence for the formation of active intermediates from RuCl3 and RuCl2(PPh3)3 with N-methylmorpholine N-oxide (NMO) and phenyliodosoacetate (PIA) as mild oxidants
TLDR
In this paper, the spectral evidence for the formation of the following active species: (1) ruthenium(VIII) in RIT-III-PIA system, (2) Ru(V) oxo species in rUThenium (III)-N -oxide system, and (3) RIT(II)-phosphine oxide complex in RUThenia(II) N-oxide system.About:
This article is published in Inorganica Chimica Acta.The article was published on 1986-07-15. It has received 5 citations till now. The article focuses on the topics: Ruthenium & Oxide.read more
Citations
More filters
Journal ArticleDOI
Selective oxidation of alkenes catalysed by ruthenium(II) complexes containing coordinated perchlorate
A.S. Kanmani,S. Vancheesan +1 more
TL;DR: In this paper, the selective homogeneous oxidation of cyclohexene with TBHP and H2O2 as oxidizing agents was investigated. And the results showed that TBHP was more effective than H 2 O 2 as an oxidizing agent.
Journal ArticleDOI
Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of LProline by Hexacyanoferrate(III) in Aqueous Alkali
TL;DR: In this article, the rate law of ruthenium(III) catalyzed oxidation of L-proline by hexacyanoferrate (III) in alkali was studied spectrophotometrically.
Journal ArticleDOI
The geometric features and spectral characteristics of some pentaamineruthenium(II) complexes.
TL;DR: The geometric and bonding parameters of Ru(II) pentaaminepyridine and cyanopyridine complexes are examined via ab initio molecular orbital calculations and show that the nitrile bonded complexes are more stable than the pyridine bonded ones by 71-625 kJ mol(-1) depending on the position of the nitrie group.
Journal ArticleDOI
Transition metals in organic synthesis: hydroformylation, reduction and oxidation: Annual survey covering the year 1986☆
Journal ArticleDOI
Oxidation of secondary alcohols byN-methylmorpholine-N-oxide (NMO) catalyzed by Ru(II) halosulfoxide complexes. A kinetic study
TL;DR: In this paper, a mechanism involving the formation of Ru(IV)oxo species as the active intermediate and a rate expression is derived for RuX2(DMSO)3DMF, which catalyzes the oxidation of secondary alcohols by NMO to ketones.
References
More filters
Journal ArticleDOI
New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
T.A. Stephenson,G. Wilkinson +1 more
TL;DR: In this article, the interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCL2(SbPh3]3], RuCl3(Pph3)2CH3OH, [RuC2(CPh3As, Ph3Sb, pyridine etc., with a carbonyl-containing solution] and the corresponding brom
Journal ArticleDOI
Electrogenerated chemiluminescence. I. Mechanism of anthracene chemiluminescence in N,N-dimethylformamide solution
Larry R. Faulkner,Allen J. Bard +1 more
TL;DR: Chandross, Longworth, and Viscoz as discussed by the authors showed that the emission spectrum comprises two or more components, the spectral distribution of the component shortest in wavelength is similar to that of anthracene fluorescence, but the others are broad, structureless, and located toward the red with respect to the first component.
Journal ArticleDOI
Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene
Paul Müller,José Godoy +1 more
TL;DR: In this paper, disubstituted acetylenes are oxidized with PhIO in presence of Ru-catalysts to afford α-diketones in 65-85% yield.
Related Papers (5)
Tetrabutylammonium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as a Noncoordinating Electrolyte: Reversible 1e− Oxidations of Ruthenocene, Osmocene, and Rh2(TM4)42+ (TM4 = 2,5-Diisocyano-2,5-dimethylhexane)
Pentamethylcyclopentadienyl Ru complexes V. Electrochemistry of CpRu halide and donor ligand complexes
Ulrich Koelle,J. Kossakowski +1 more