Journal ArticleDOI
Spectroscopic studies of ionic solvation. X. Study of the solvation of sodium ions in nonaqueous solvents by sodium-23 nuclear magnetic resonance
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This article is published in Journal of the American Chemical Society.The article was published on 1971-11-01. It has received 157 citations till now. The article focuses on the topics: Solvation & Ionic bonding.read more
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The acceptor number — A quantitative empirical parameter for the electrophilic properties of solvents
TL;DR: In this article, the acceptor number of 34 solvents has been derived from 31P-n.m.r. measurements of triethylphosphine oxide dissolved in the respective solvent.
Journal ArticleDOI
Empirical Parameters of Solvent Polarity as Linear Free‐Energy Relationships
TL;DR: In this article, a summary of the 24 most important empirical parameters of solvent polarity and the table of ET(30) values for 151 solvents are presented, in addition to examples of the application of these values, attempts to improve the LFE correlations of singular empirical parameters with the aid of multiparametric equations are described.
PatentDOI
Stable room-temperature sodium-sulfur battery
Lynden A. Archer,Shuya Wei +1 more
TL;DR: A room-temperature sodium–sulfur battery that uses a microporous carbon–Sulfur composite cathode, and a liquid carbonate electrolyte containing the ionic liquid 1-methyl-3-propylimidazolium-chlorate tethered to SiO2 nanoparticles that can cycle stably at a rate of 0.5 C is reported.
Journal ArticleDOI
Electrochemical and XPS studies toward the role of monomeric and polymeric sulfonate counterions in the synthesis, composition, and properties of poly(3,4-ethylenedioxythiophene)
Gianni Zotti,Sandro Zecchin,Gilberto Schiavon,Frank Louwet,L. Groenendaal,Xavier Crispin,Wojciech Osikowicz,William R. Salaneck,Mats Fahlman +8 more
TL;DR: In this paper, the authors compared electrochemically prepared poly(3,4-ethylenedioxythiophene) (PEDT) poly(styrenesulfonate) (PSS), produced from acidic (PSSH) and basic (PSSNa) PSS, was characterized by cyclic voltammetry CV, UV−vis spectroscopy, in situ conductivity, and XPS analysis.
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