Spin-crossover nanoparticles and nanocomposite materials
Lionel Salmon,Laure Catala +1 more
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TLDR
In this article, the state of the art of the elaboration and the application of nanoparticles and nanohybrid/nanocomposite materials based on spin-crossover (SCO) complexes is reported.About:
This article is published in Comptes Rendus Chimie.The article was published on 2018-12-01 and is currently open access. It has received 76 citations till now. The article focuses on the topics: Nanocomposite.read more
Citations
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Journal ArticleDOI
Bond-random model of spin-crossover compounds: similarities and differences from spin glasses
Iurii Gudyma,Vadym Yarema +1 more
TL;DR: In this article, the Ising-like model of spin-crossover solid compounds with random bonds has been studied by the mean-field replica symmetry approximation, and an exact solution to the problem is found and analyzed.
Journal ArticleDOI
Dynamical Mechanical Analysis and Micromechanics Simulations of Spin-Crossover@Polymer Particulate Composites: Toward Soft Actuator Devices
S.E. Alavi,Baptiste Martin,Yue Wen Zan,Xinyu Yang,Mario Piedrahita-Bello,William Nicolazzi,Jean-François Ganghoffer,Lionel Salmon,Gábor Molnár,Azzedine Bousseksou +9 more
TL;DR: In this article , the authors investigated the interplay between the thermomechanical and spin-crossover properties of a series of stimuli-responsive polymer composites consisting of Fe(NH2trz)3]SO4 and Fe(Htrz)(trz2]BF4 particles embedded in thermoplastic polyurethane, TPU, and poly(vinylidene fluoride-trifluoroethylene), P(VDF-TrFE), matrices.
Book ChapterDOI
Ising-Like Model of Nanosize Spin-Crossover Molecular Crystals
Iurii Gudyma,Artur Maksymov +1 more
TL;DR: In this paper, the properties of spin-crossover nanoparticles were investigated within a framework of Ising-like model by involving the Monte Carlo simulation tools, a thermal transition of spincrossover solids with local random fields of various statistical characteristics and without stochastic origins has been analyzed.
Journal ArticleDOI
Spin State Bistability in (Mn, Zn) Doped (Fe(Phen)2(Ncs)2) Molecular Thin Film Nanocrystals on Quartz
Journal ArticleDOI
Spin state bistability in (Mn, Zn) doped Fe(phen)2(NCS)2 molecular thin film nanocrystals on quartz
TL;DR: In this article , the spin transition temperature and loop width are found to be critically dependent on metal doping and suggested the possibility of tuning these parameters in spin-crossover thin films to design future spin-based devices.
References
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Theory, Production and Mechanism of Formation of Monodispersed Hydrosols
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Spin-Transition Polymers: From Molecular Materials Toward Memory Devices
O. Kahn,C. Jay Martinez +1 more
TL;DR: In this article, the transition temperature of transition metal compounds can be fine tuned using an approach based on the concept of a molecular alloy, and it is possible to design a compound for which room temperature falls in the middle of the thermal hysteresis loop.
Journal ArticleDOI
Photoinduced Magnetization of a Cobalt-Iron Cyanide
TL;DR: The magnetization in the ferrimagnetic region below 16 kelvin was substantially increased after illumination and could be restored almost to its original level by thermal treatment and these effects are thought to be caused by an internal photochemical redox reaction.
Journal ArticleDOI
Amphiphilic Block Copolymers in Structure-Controlled Nanomaterial Hybrids
TL;DR: Amphiphilic block copolymers (ABCs) represent a new class of functional polymers that are unique building blocks serving a number of applications mainly related to the energetic and structural control of materials interfaces as discussed by the authors.
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Molecular spin crossover phenomenon: recent achievements and prospects
TL;DR: This critical review discusses recent work in the field of molecule-based spin crossover materials with a special focus on these emerging issues, including chemical synthesis, physical properties and theoretical aspects as well (223 references).