Spin-crossover nanoparticles and nanocomposite materials
Lionel Salmon,Laure Catala +1 more
Reads0
Chats0
TLDR
In this article, the state of the art of the elaboration and the application of nanoparticles and nanohybrid/nanocomposite materials based on spin-crossover (SCO) complexes is reported.About:
This article is published in Comptes Rendus Chimie.The article was published on 2018-12-01 and is currently open access. It has received 76 citations till now. The article focuses on the topics: Nanocomposite.read more
Citations
More filters
Journal ArticleDOI
OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes.
Rangsiman Ketkaew,Yuthana Tantirungrotechai,Phimphaka Harding,Guillaume Chastanet,Philippe Guionneau,Mathieu Marchivie,David J. Harding +6 more
TL;DR: OctaDist computes the octahedral distortion parameters initially designed in the context of the spin-crossover phenomenon and denoted ζ, Σ, and Θ from standard structural files.
Journal ArticleDOI
Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale
TL;DR: This review aims to summarise the chemical strategies that have guided the design of conductive metal-organic frameworks and the identified opportunities for further development and showcase relevant examples of functional devices that have received increasing attention from researchers.
Journal ArticleDOI
Spin crossover polymer composites, polymers and related soft materials
Alejandro Enríquez-Cabrera,Amalia Rapakousiou,Mario Piedrahita Bello,Gábor Molnár,Lionel Salmon,Azzedine Bousseksou +5 more
TL;DR: In this article, the synthesis, properties and applications of spin crossover polymer composites, polymers and some related soft materials are reviewed, with a particular attention paid on the influence of the polymer matrix on the spin crossover properties and on the use of active polymers for development of synergies between the properties of the matrix and the load.
Journal ArticleDOI
Spin crossover and valence tautomerism conductors
TL;DR: In this paper, the authors present the recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials as well as synergistic and cooperative properties of bistability and conductivity.
Journal ArticleDOI
Confined Crystallization of Spin‐Crossover Nanoparticles in Block‐Copolymer Micelles
Christoph Göbel,Christian Hils,Markus Drechsler,Dirk Baabe,Andreas Greiner,Holger Schmalz,Birgit Weber +6 more
TL;DR: Nanoparticles of the spin‐crossover coordination polymer [FeL(bipy)]n were synthesized by confined crystallization within the core of polystyrene‐block‐poly(4‐vinylpyridine) (PS‐b‐P4VP) diblock copolymer micelles allowing thermal treatment without disintegration of their structure.
References
More filters
Journal ArticleDOI
Room Temperature Magnetic Detection of Spin Switching in Nanosized Spin-Crossover Materials
Tran Quang Hung,Ferial Terki,Souleymane Kamara,Mourad Dehbaoui,Salam Charar,Brajalal Sinha,CheolGi Kim,Philippe Gandit,Il'ya A. Gural'skiy,Gábor Molnár,Lionel Salmon,Helena J. Shepherd,Azzedine Bousseksou +12 more
TL;DR: The synthesis and investigation of nanoscale spin-crossover particles at reduced length scales is central to the exploration of fundamental effects of size reduction in these systems, but also for the development of new functional materials with applications, including guest molecule sensing, memory devices, and molecular switches.
Journal ArticleDOI
Water effect on the spin-transition behavior of Fe(II) 1,2,4-triazole 1D chains embedded in pores of MCM-41
Tian Zhao,Laure Cuignet,Laure Cuignet,Marinela M. Dîrtu,Mariusz Wolff,Vojislav Spasojević,Ishtvan Boldog,Aurelian Rotaru,Yann Garcia,Christoph Janiak +9 more
TL;DR: In this article, the spin crossover behavior of the SCO-1@MCM composites was investigated by temperature-variable 57Fe Mossbauer spectroscopy, magnetic and differential scanning calorimetry measurements and optical reflectivity.
Journal ArticleDOI
Micromachining-compatible, facile fabrication of polymer nanocomposite spin crossover actuators
Maria Dolores Manrique-Juarez,Fabrice Mathieu,Adrian Laborde,Sylvain Rat,Victoria Shalabaeva,Philippe Demont,Olivier Thomas,Lionel Salmon,Thierry Leichle,Liviu Nicu,Gábor Molnár,Azzedine Bousseksou +11 more
TL;DR: In this article, spin crossover particles of 85 nm mean size are dispersed in an SU-8 polymer matrix and spray-coated onto silicon microcantilevers, which exhibit well-reproducible actuation upon the thermally induced spin transition.
Journal ArticleDOI
Light induced modulation of charge transport phenomena across the bistability region in [Fe(Htrz)2(trz)](BF4) spin crossover micro-rods.
Constantin Lefter,Reasmey P. Tan,Julien Dugay,Simon Tricard,Gábor Molnár,Lionel Salmon,Julian Carrey,Aurelian Rotaru,Azzedine Bousseksou +8 more
TL;DR: The effect of light irradiation on the electrical conductance of micro-rods of the spin crossover [Fe(Htrz)2(trz)](BF4) network, organized between interdigitated gold electrodes, is studied.
Journal ArticleDOI
On the stability of spin crossover materials: From bulk samples to electronic devices
Constantin Lefter,Constantin Lefter,Reasmey P. Tan,Simon Tricard,Julien Dugay,Gábor Molnár,Lionel Salmon,Julian Carrey,Aurelian Rotaru,Azzedine Bousseksou +9 more
TL;DR: In this paper, the integration of micro-rods of the [Fe(Htrz)2(trz)](BF4) spin crossover compound into an electronic switch-type device was reported.