Spin-crossover nanoparticles and nanocomposite materials
Lionel Salmon,Laure Catala +1 more
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TLDR
In this article, the state of the art of the elaboration and the application of nanoparticles and nanohybrid/nanocomposite materials based on spin-crossover (SCO) complexes is reported.About:
This article is published in Comptes Rendus Chimie.The article was published on 2018-12-01 and is currently open access. It has received 76 citations till now. The article focuses on the topics: Nanocomposite.read more
Citations
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OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes.
Rangsiman Ketkaew,Yuthana Tantirungrotechai,Phimphaka Harding,Guillaume Chastanet,Philippe Guionneau,Mathieu Marchivie,David J. Harding +6 more
TL;DR: OctaDist computes the octahedral distortion parameters initially designed in the context of the spin-crossover phenomenon and denoted ζ, Σ, and Θ from standard structural files.
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Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale
TL;DR: This review aims to summarise the chemical strategies that have guided the design of conductive metal-organic frameworks and the identified opportunities for further development and showcase relevant examples of functional devices that have received increasing attention from researchers.
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Spin crossover polymer composites, polymers and related soft materials
Alejandro Enríquez-Cabrera,Amalia Rapakousiou,Mario Piedrahita Bello,Gábor Molnár,Lionel Salmon,Azzedine Bousseksou +5 more
TL;DR: In this article, the synthesis, properties and applications of spin crossover polymer composites, polymers and some related soft materials are reviewed, with a particular attention paid on the influence of the polymer matrix on the spin crossover properties and on the use of active polymers for development of synergies between the properties of the matrix and the load.
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Spin crossover and valence tautomerism conductors
TL;DR: In this paper, the authors present the recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials as well as synergistic and cooperative properties of bistability and conductivity.
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Confined Crystallization of Spin‐Crossover Nanoparticles in Block‐Copolymer Micelles
Christoph Göbel,Christian Hils,Markus Drechsler,Dirk Baabe,Andreas Greiner,Holger Schmalz,Birgit Weber +6 more
TL;DR: Nanoparticles of the spin‐crossover coordination polymer [FeL(bipy)]n were synthesized by confined crystallization within the core of polystyrene‐block‐poly(4‐vinylpyridine) (PS‐b‐P4VP) diblock copolymer micelles allowing thermal treatment without disintegration of their structure.
References
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Reproducible on–off switching of the light emission from the electroluminescent device containing a spin crossover complex
TL;DR: In this paper, the authors examined the mechanism of a reproducible on-off switching of light emission from a novel organic electroluminescent (EL) device consisting of a spin crossover complex of [Fe(dpp)2]-BF4)2 (dpp = 2,6-di(pyrazol-1-yl)pyridine) and chlorophyll a.
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Pressure and temperature sensors using two spin crossover materials
Catalin-Maricel Jureschi,Jorge Linares,Ayoub Boulmaali,Pierre-Richard Dahoo,Aurelian Rotaru,Yann Garcia +5 more
TL;DR: It is conjectured from numerical results obtained by mean field approximation applied to a Ising-like model that using two different spin crossover compounds containing switching molecules with weak elastic interactions it is possible to simultaneously measure P and T.
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Soft lithographic patterning of spin crossover complexes. Part 1: fluorescent detection of the spin transition in single nano-objects
Carlos M. Quintero,Il'ya A. Gural'skiy,Il'ya A. Gural'skiy,Lionel Salmon,Gábor Molnár,Christian Bergaud,Azzedine Bousseksou +6 more
TL;DR: In this paper, thin films and nano-patterns of the compound [FeII(hptrz)3]-OTs2 doped with acridine orange were elaborated by spin coating and soft-lithography, respectively.
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Femtosecond spin-state photoswitching of molecular nanocrystals evidenced by optical spectroscopy.
TL;DR: This result provides proof-of-principle for femtosecond switching at the nanoscale in SCO materials showing photomagnetic and photochromic responses, and takes advantage of growing knowledge in the field of ultrafast chemical physics.
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Soft lithographic patterning of spin crossover nanoparticles.
Christophe Thibault,Christophe Thibault,Gábor Molnár,Gábor Molnár,Lionel Salmon,Lionel Salmon,Azzedine Bousseksou,Azzedine Bousseksou,Christophe Vieu,Christophe Vieu +9 more
TL;DR: It is shown that the use of an aprotic solvent (n-octane) may lead to successful results in fabricating micropatterns of spin crossover nanoparticles of Fe(NH(2)trz) over a large area.