Journal ArticleDOI
Spontaneous resolution of 3D chiral hexadecavanadate-based frameworks incorporating achiral flexible and rigid ligands
TLDR
In this paper, mixed flexible and rigid achiral ligands were introduced into the chiral polyoxometalate-based skeleton, leading to the isolation of two enantiomerically 3D chiral hexadecavanadate derivatives.Abstract:
Introducing of mixed flexible and rigid achiral ligands into the hexadecavanadate skeleton leads to the isolation of two enantiomerically 3D chiral hexadecavanadate derivatives, which represent the first example of chiral polyoxometalate-based framework functionalized with mixed flexible and rigid achiral ligands.read more
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Polyoxometalate-directed assembly of various multinuclear metal–organic complexes with 4-amino-1,2,4-triazole and selective photocatalysis for organic dye degradation
TL;DR: A series of polyoxometalate (POM)-based metal-organic complexes containing multinuclear Cu(II) clusters with a 4-amino-1,2,4-triazole (4-atrz) ligand have been synthesized by selectively adding additional citric acid or boric acid under hydrothermal conditions as mentioned in this paper.
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Turn helical motifs from pair to single entangled double helixes in a cobalt-vanadate system via introduction of a V-shaped ligand.
TL;DR: Two novel helical compounds based on polyoxovanadates have been synthesized under identical hydrothermal conditions, providing two structurally different helical motifs due to introduction of a V-shaped bimb ligand in 2.
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The design, syntheses and characterization of a series of hybrids based on polyoxometalates and metal complexes
La-Mei Wang,Yan Wang,Yan Wang,Yong Fan,Li-Na Xiao,Yang-Yang Hu,Zhong-Min Gao,Da-Fang Zheng,Xiao-Bing Cui,Ji-Qing Xu +9 more
TL;DR: In this paper, a new hybrid compound based on polyoxometalates and transition metal complexes has been synthesized and characterized, which is the first hybrid compound with a supramolecular structure constructed from bicapped Keggin POMs and metal.
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Porous Polymers Derived from Octavinylsilsesquioxane by Cationic Polymerization
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Substituent position-induced diverse architectures of polyoxovanadate-based hybrid materials constructed from a linear trinuclear transition metal complex and a hexanuclear [V6O18]6− cluster
TL;DR: In this article, four new hexavanadate cluster-based hybrid materials were synthesized under hydrothermal conditions by the reaction of transition metal salts, amino-triazole ligands and sodium metavanadates.
References
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Ordered porous materials for emerging applications
TL;DR: The past decade has seen significant advances in the ability to fabricate new porous solids with ordered structures from a wide range of different materials, which has resulted in materials with unusual properties and broadened their application range beyond the traditional use as catalysts and adsorbents.
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Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
TL;DR: In this critical review the synthetic and design approaches to the many polyoxometalate cluster types are presented encompassing all the sub-types of polyxometalates including, isopolyoxometAlates, heteropolyoxometricalates, and reduced molybdenum blue systems.
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