Journal ArticleDOI
Stereochemistry of electroreductions of bromocyclopropanes: 1-asymmetric electrochemical synthesis by reduction at a mercury cathode in the presence of adsorbed alkaloïds
TLDR
In this article, the electrochemical properties of 1-bromo-2,2,diphenylcyclopropane carboxylic acid, its methyl ester and 1,1-dibromo 2,2-diphexagonalcyclopropanes were investigated in the presence of strongly adsorbed alkaloids: yohimbine, emetine, brucine, strychnine and methylstrychninium cations.About:
This article is published in Tetrahedron.The article was published on 1982-01-01. It has received 25 citations till now. The article focuses on the topics: Protonation & Brucine.read more
Citations
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Journal ArticleDOI
Asymmetric catalysis at chiral metal surfaces.
Journal ArticleDOI
Enantioselective synthesis using chiral heterogeneous catalysts.
TL;DR: The application of solid chiral catalysts for the enantioselective synthesis of chiral molecules is reviewed in this article, where the scope and limitations of these catalytic systems and their value for the synthetic organic chemist are discussed.
Journal ArticleDOI
Asymmetric Electrochemical Catalysis
TL;DR: This concept article is expected to provide readers with the general concepts and perspectives of each chiral electrochemical catalysis mode, and to indicate the potential and future development of asymmetric electrochemicalCatalysis.
Journal ArticleDOI
Stereoselective Hydrodehalogenation via a Radical-Based Mechanism Involving T-Shaped Chiral Nickel(I) Pincer Complexes
TL;DR: These new chiral nickel(I) complexes were found to catalyze the asymmetric hydrodehalogenation of geminal dihalogenides with moderate to good enantiomeric excess values using LiEt3 BH as reductant.
References
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Journal ArticleDOI
Cyclopropanes. XV. The Optical Stability of 1-Methyl-2,2-diphenylcyclopropyllithium
Journal ArticleDOI
Cyclopropanes. XXVI. Electrolytic reduction of optically active 1-halo-1-methyl-2,2-diphenylcyclopropanes
Journal ArticleDOI
Asymmetric, cathodic reduction of acetylpyridines
Journal ArticleDOI
Synthese asymetrique par voie electrochimique. Etude de l'influence des differents parametres sur le rendement optique
M. Jubault,E. Raoult,D. Peltier +2 more
TL;DR: In this paper, le rendement optique maximal is obtenu en presence of tres faibles quantites d'un alcaloide convenablement choisi; le pouvoir inducteur de ce dernier est fonction de son adsorption sur le mercure and de la nature du substrat.
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