Journal ArticleDOI
Stereoselective Transformation of Enantiopure Cyclohexenol into cis-Hydrindan. An Enantioselective Formal Total Synthetic Route to (+)-Pumiliotoxin C
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This article is published in Journal of Organic Chemistry.The article was published on 1996-11-29. It has received 33 citations till now.read more
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Quinoline, quinazoline and acridone alkaloids
TL;DR: This review covers the isolation, structure determination, synthesis and biological activity of quinoline, quinazoline and acridone alkaloids from plant, microbial and animal sources.
Journal ArticleDOI
Reserpine: A Challenge for Total Synthesis of Natural Products
Fen-Er Chen,Jian Huang +1 more
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Total Synthesis of Rubriflordilactone B
TL;DR: The first and asymmetric total synthesis of Rubriflordilactone A, a bisnortriterpenoid isolated from Schisandra rubriflora, has been accomplished in a convergent manner.
Journal ArticleDOI
Total synthesis of rubriflordilactone A.
TL;DR: The first and asymmetric total synthesis of Rubriflordilactone A, a bisnortriterpenoid isolated from Schisandra rubriflora, has been accomplished in a convergent manner as discussed by the authors.
References
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Rapid chromatographic technique for preparative separations with moderate resolution
Abstract: (11) Potassium ferricyanide has previously been used to convert w'c-1,2-dicarboxylate groups to double bonds. See, for example, L. F. Fieser and M. J. Haddadln, J. Am. Chem. Soc., 86, 2392 (1964). The oxidative dldecarboxylation of 1,2-dlcarboxyllc acids is, of course, a well-known process. See Inter alia (a) C. A. Grob, M. Ohta, and A. Weiss, Helv. Chim. Acta, 41, 1911 (1958); and (b) E. N. Cain, R. Vukov, and S. Masamune, J. Chem. Soc. D, 98 (1969).
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Über Steroide und Sexualhormone. 160. Mitteilung. 2α, 3α‐ und 2β, 3β‐Oxido‐chlolestane; Konfiguration der 2‐Oxy‐cholestane
Andor Furst,Pl. A. Plattner +1 more
TL;DR: In this paper, die Konfiguration der beiden 2,3-Cholesten-oxyde und 2,2-Oxy-cholestane bestimmt.
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Diastereoface-discriminative metal coordination in asymmetric synthesis: D-pantolactone as practical chiral auxiliary for Lewis acid catalyzed Diels-Alder reactions☆
TL;DR: In this article, the acrylate of commercial D-pantolactone was added to cyclopentadiene, isoprene and butadiene with high diastereofacial selectivity.
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Palladium-catalyzed substitutions of triflates derived from tyrosine-containing peptides and simpler hydroxyarenes forming 4-(diethoxyphosphinyl)phenylalanines and diethyl arylphosphonates
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N-Hydroxypyridine-2-thione carbamates as aminyl and aminium radical precursors. Cyclizations for synthesis of the pyrrolidine nucleus
Martin Newcomb,Thomas M. Deeb +1 more
TL;DR: A partir de [butyl pentene-4yl carbamoyloxy]-1 1H-pyridinethione-2, obtention du radical butyl pentenes4yl aminyle qui permet d'obtenir les butyl-1 methyl-2 pyrrolidine et butyl 1 pyridyl-2thiomethyl -2th-iomethemyl-two pyrrinidine as discussed by the authors.