Journal ArticleDOI
Structure and Exchange Processes in Some Inorganic Fluorides by Nuclear Magnetic Resonance1
E. L. Muetterties,W. D. Phillips +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1959-03-01. It has received 171 citations till now.read more
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Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds
TL;DR: In this paper, the WKB expression for tunneling frequencies permits correlation of these frequencies for members of homologous series of molecules, and the necessary data required are the tunneling rate for one member of the series, and structural parameters and vibrational frequencies for all members of interest.
Journal ArticleDOI
The narrowing of NMR spectra of solids by high-speed specimen rotation and the resolution of chemical shift and spin multiplet structures for solids
Journal ArticleDOI
Effect of electron lone-pairs on nuclear spin–spin coupling constants
TL;DR: In this article, the nature and types of lone-pair effects on nuclear spin coupling constants are reviewed in the context of a localized bond description of molecular electronic structure, with particular attention paid to couplings involving H, C, N, F and P nuclei, organized in a systematic manner into nine categories.
Journal ArticleDOI
Structure and Dipole Moment for SF4
W. M. Tolles,William D. Gwinn +1 more
TL;DR: The microwave spectrum and structure of sulfur tetrafluoride has been determined in this article, and the dipole moment was determined from the Stark effect to be 0.632±0.003 debye.
Journal ArticleDOI
17O NMR in simple oxides
T. J. Bastow,S. N. Stuart +1 more
TL;DR: The following binary metal oxides have yielded high-resolution 17O nuclear magnetic resonance (NMR) spectra, obtained by magic-angle spinning (MAS) without isotopic enrichment: α-Al2O3, TiO2 (anatase and rutile), Ti2O 3, monoclinic VO2, Cu2O, ZnO, tetragonal and monocallinic ZrO2, Ag2O 2, tetragonagonal SnO, hexagonal La 2O 3, hexagonal Na β-Al 2