Journal ArticleDOI
Study on the mechanism of chiral recognition with molecularly imprinted polymers
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TLDR
In this paper, the chiral recognition mechanism with molecularly imprinted polymers (MIPs) in aqueous environment was elucidated by a self-assembly mechanism, which includes the pre-organizing functional monomers around template before polymerization process.About:
This article is published in Analytica Chimica Acta.The article was published on 2003-08-11. It has received 65 citations till now. The article focuses on the topics: Molecularly imprinted polymer & Methacrylic acid.read more
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Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003
Cameron Alexander,Håkan S. Andersson,Lars I. Andersson,Richard J. Ansell,Nicole Kirsch,Ian A. Nicholls,John O’Mahony,Michael J. Whitcombe +7 more
TL;DR: In the presentation of the assembled references, a section presenting reviews and monographs covering the area is followed by papers dealing with fundamental aspects of molecular imprinting and the development of novel polymer formats.
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Synthetic strategies for the generation of molecularly imprinted organic polymers.
TL;DR: In this review the main synthetic strategies used in the preparation of imprinted organic polymers are described in terms of the chemical principlesused in the templating step and are classified as covalent, semi-covalents, non-cavalent, metal-mediated and non-polar.
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How to find effective functional monomers for effective molecularly imprinted polymers
Kal Karim,Florent Breton,Régis Rouillon,Elena V. Piletska,Antonio Guerreiro,Iva Chianella,Sergey A. Piletsky +6 more
TL;DR: This review covers work developed in understanding molecular imprinting mechanisms and presents different strategies utilised in optimising MIP design.
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Characterization of binding sites in molecularly imprinted polymers
TL;DR: A review of the progress of the understanding of the molecular recognition binding sites beyond the usual description of adsorption isotherms is given in this article, where analytical and numerical methods used for calculating the adsorbing isotherm and the adsoreption energy distribution, as a quantitative measure of the imprinted polymer heterogeneity, are also discussed.
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Optical interrogation of molecularly imprinted polymers and development of MIP sensors: a review
TL;DR: This article reviews the progress and developments achieved in the past five years in the application of optical analytical techniques to the evaluation of molecularly imprinted polymer (MIP) characteristics and provides insight into the various approaches to the optical interrogation of MIPs.
References
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Journal ArticleDOI
Molecular Imprinting in Cross‐Linked Materials with the Aid of Molecular Templates— A Way towards Artificial Antibodies
TL;DR: In this article, the authors present a method analogous to a mechanism of antibody formation proposed earlier, by which in the presence of interacting monomers a cross-linked polymer is formed around a molecule that acts as a template.
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Separation of enantiomers: needs, challenges, perspectives☆
TL;DR: The present implications of their chiral nature and necessity of separating enantiomers are summarised in this article and a brief overview of the actual approaches to perform enantioseparations at analytical and preparative scale is given.
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Highly enantioselective and substrate-selective polymers obtained by molecular imprinting utilizing noncovalent interactions. NMR and chromatographic studies on the nature of recognition
TL;DR: Preparation de polymeres methacryliques hautement enantioselectifs and substrats selectifs par impression moleculaire de derives de la L-phenylalanine, selectivite gouvernee par les interactions entre le substrat et la phase stationnaire-polymere and par la nature des substituants de la phenylalanines as discussed by the authors.
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Surface silanols in silica-bonded hydrocarbonaceous stationary phases
Avi Nahum,Csaba Horváth +1 more
TL;DR: In this paper, a dual binding model was proposed to predict the temperature dependence of retention under various conditions as far as the nature of the stationary phase and the eluent composition are concerned.