Journal ArticleDOI
The Application of Ceric Ammonium Nitrate in the Synthesis of Carbodiazones
TLDR
In this paper, the bisaryl carbodiazone compounds from the aryl substituted carbazides with Ceric Ammonium Nitrate (CAN) were reported for the first time in excellent yields.About:
This article is published in Synthetic Communications.The article was published on 2000-04-01. It has received 14 citations till now. The article focuses on the topics: Ceric ammonium nitrate.read more
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Synthesis, oxidation and dehydrogenation of cyclic N,O‐ and N,S‐acetals. Part III. Transformation of N,O‐acetals: 3‐acyl‐1,3,4‐oxadiazolines
TL;DR: In this article, simple, convenient and efficient dehydrogenations of 3-acyl-1,3,4-oxadiazolines to oxadiazoles by treatment with potassium permanganate, or more conveniently, with ammonium cerium(IV) nitrate (CAN) are presented.
Journal ArticleDOI
CAN-mediated oxidative cleavage of 4-aryl-3,4-dihydroxypiperidines
TL;DR: In this article, a CAN-mediated oxidative cleavage of 4-aryl-3,4-dihydroxypiperidines 2Aa-Be to β-amino carbonyl compounds 3Aa − Be and 4Aa - Be in different ratios is described.
Journal ArticleDOI
Photochemical generation and trapping of radicals from bisphenyl carbodiazone
TL;DR: In this paper, UV irradiation at 350 nm of bisphenyl carbodiazone creates nitrogen, phenyl and (phenyldiazenyl) carbonyl radicals under mild conditions.
Journal ArticleDOI
CAN-mediated rearrangement of 4-benzhydrylidenepiperidines
TL;DR: In this article, 1-substituted phenyl-(4-phenylpiperidin-4-yl)methanones are synthesized in modest overall yields starting from the reaction of different 4-benzhydrylidenepiperidines via CAN-mediated rearrangement.
Journal ArticleDOI
Aminohydroxylation and dihydroxylation of 4-aryl-1,2,5,6-tetrahydropyridines
TL;DR: Substituted 3-amino-4-aryl- 4-hydroxypiperidines and 4- Daryl-3,4-dihydroxypipersidines are synthesized in the modest overall yields starting from the regio- and stereoselective trans-aminohydroxylation and dihydroxylations of 4-aryl, 2,5,6-tetrahydropyridines via CAN-mediated oxidative addition and hydrogenation.
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