Journal ArticleDOI
The reversible adduct formation of group III trialkyls with relatively involatile phosphines; X-ray crystal structures of (Me3M)2·(Ph2PCH2)2 (M = Al, Ga, In) and (Me3Al)3·(Ph2PCH2CH2)2PPh
Donald C. Bradley,Halina Chudzynska,Marc M. Faktor,Dario M. Frigo,Michael B. Hursthouse,Bilquis Hussain,Lesley M. Smith +6 more
TLDR
The following adducts of Group III trialkyls with phosphines have been prepared, either by direct reaction in hydrocarbon solution or by displacement of ether from the metal Trialkyl etherate: Me3M·PPh3 (M = Ga, In); Me3In·P(2-MeC6H4)3; (R3M)2·(Ph2PCH2)2 (RAbout:
This article is published in Polyhedron.The article was published on 1988-01-01. It has received 48 citations till now.read more
Citations
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Journal ArticleDOI
Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
TL;DR: The difference between the covalent and the dative bond becomes apparent only after the orbital coefficients have been analyzed as discussed by the authors, which may explain why many structural chemists seem reluctant to distinguish between the two types of bonds.
Journal ArticleDOI
Group 13 compounds incorporating Salen ligands.
TL;DR: Although reactions such as oxirane and lactide polymerizations are fairly well-known now with five- and six-coordinate aluminum compounds, the potential of these compounds has only begun to be developed.
Journal ArticleDOI
Kovalente und dative Bindungen zu Hauptgruppenmetallen, eine nützliche Unterscheidung
TL;DR: In this paper, a gute Basis fur das Verstandnis der Strukturen einer Fulle von Hauptgruppenmetallverbindungen is discussed, das sich physikochemischen Eigenschaften kovalenter and dativer Bindungen deutlich unterscheiden konnen.
Journal ArticleDOI
Synthese und Molekülstruktur des Tetrakis[bis(trimethylsilyl)methyl]digallans(4) mit GalliumGallium-Bindung
TL;DR: In this article, the reaction of Ga2Br4·2dioxane with four equivalents of bis(trimethylsilyl)methyllithium yields tetrakis[bis[bis-trimmethyll)methyl]digallane(4) (1), which precipitates from n-pentane as well-shaped yellow crystals.
Journal ArticleDOI
Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands
TL;DR: Polydentate ligand complexes containing neutral or charged N, O, C, or S donor groups in addition to phosphino or arsino donor groups are included, but charged P or As (phosphides, arsenides, phosphinomethanides etc.) ligands are excluded.
References
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Journal ArticleDOI
The Use of Metal‐Organics in the Preparation of Semiconductor Materials I . Epitaxial Gallium‐ V Compounds
H. M. Manasevit,W. I. Simpson +1 more
TL;DR: In this article, the decomposition of alkyl-gallium compounds in the presence of arsine, phosphine, arsinesinephosphine, and stibine mixtures has been used for compound semiconductor film growth compatible with methods used for the growth of elemental semiconductors.
Journal ArticleDOI
Synthesis and x-ray crystal structures of hexakis(trimethylphosphine)tris-.mu.-methylene-diruthenium(III) and its mono- and dicationic derivatives
Journal ArticleDOI
Adducts in the growth of III–V compounds
TL;DR: Adducts have become increasingly important as precursors in MOVPE, particularly for the growth of indium compounds, and their properties and results have been obtained for the growing of compounds of the Ga-In-As-P system as mentioned in this paper.
Journal ArticleDOI
The Use of Metalorganics in the Preparation of Semiconductor Materials V . The Formation of In‐Group V Compounds and Alloys
H. M. Manasevit,W. I. Simpson +1 more
Journal ArticleDOI
Adducts of trimethylindium with amine and phosphine ligands; X-ray crystal structure of Me3InNHCMe2(CH2)3CMe2, Me3InN(CH2CH2)3N and Me3InNHMe(CH2)2NHMeInMe3
TL;DR: In this paper, a linear polymer of alternating Me3In and N(CH2CH2)3N units was shown to have a planar structure and the indium is almost perfectly trigonal bipyramidal and the InN bonds are very long.
Related Papers (5)
Adducts of trimethylaluminium with phosphine ligands: X-ray crystal structures of Me3AlPPh3 and Me3AlP(o-tolyl)3
Derk A. Wierda,Andrew R. Barron +1 more