Journal ArticleDOI
Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
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The difference between the covalent and the dative bond becomes apparent only after the orbital coefficients have been analyzed as discussed by the authors, which may explain why many structural chemists seem reluctant to distinguish between the two types of bonds.Abstract:
Textbooks of inorganic chemistry describe the formation of adducts by coordination of an electron donor to an electron acceptor, often using the amine-boranes, X3N → BY3, as examples. In the Lewis (electron dot) formulas of the compounds, the dative bond in H3N → BH3 and the covalent bond in H3CCH3 are both represented by a shared electron pair. In the simple molecular orbital or valence bond models the wave functions of both electron pairs would be constructed in the same manner from the appropriate sp3 type atomic orbitals on the bonded atoms; the difference between the covalent and the dative bond becomes apparent only after the orbital coefficients have been analyzed. This may be the reason why many structural chemists seem reluctant to distinguish between the two types of bonds. The object of this article is to remind the reader that the physiocochemical properties of covalent and dative bonds may be – and often are – quite different, and to show that a distinction between the two provides a basis for understanding the structures of a wide range of main group metal compounds.read more
Citations
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Ammonia-borane and related compounds as dihydrogen sources.
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Amine- and phosphine-borane adducts: new interest in old molecules.
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NHCs in Main Group Chemistry.
Vitaly Nesterov,Dominik Reiter,Prasenjit Bag,Philipp Frisch,Richard Holzner,Amelie Porzelt,Shigeyoshi Inoue +6 more
TL;DR: A general overview of the chemistry of low-coordinate main group element compounds, basic synthetic approaches, key features of NHC-main group element adducts, and might be useful for the broad research community are given.
Journal ArticleDOI
N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry.
TL;DR: The availability of a large number of novel NHC adducts has not only produced new varieties of already existing ligand classes but has also allowed establishment of numerous complexes with unusual and often unprecedented element-metal bonds.
Journal ArticleDOI
Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids
Ralf Tonner,Gernot Frenking +1 more
TL;DR: The calculations show that the experimentally known compounds 2-5 and 8 chemically behave like molecules L(2)C which have two L-->C donor-acceptor bonds and a carbon atom with two electron lone pairs.
References
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Book
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TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Journal ArticleDOI
Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
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Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds
TL;DR: The average lengths of bonds involving the elements H, B, C, N, O, F, Si, P, S, Cl, As, Se, Br, Te, and l in organic compounds are reported in this article.
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The Donor-Acceptor Approach to Molecular Interactions
TL;DR: In this article, an extension of the donor-acceptor concept, characterized by the comparison between equilibrium structures in different molecular environments, is presented, in which changes in the positions of the nuclei are taken into account and the question of the nature of the molecular forces is no longer important.