Journal ArticleDOI
Thermal transitions and mechanical properties of films of chemically prepared polyaniline
TLDR
In this article, the glass transition temperature (Tg) of polyaniline films in emeraldine base form was determined and characterized for the first time to be in the range of ∼ 105-220°C for the films containing ∼ 16-0% of 1-methyl-2-pyrrolidinone (NMP) residual solvent, respectively.About:
This article is published in Polymer.The article was published on 1992-01-01. It has received 207 citations till now. The article focuses on the topics: Polyaniline & Differential scanning calorimetry.read more
Citations
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Journal ArticleDOI
Enhancement of Corrosion Protection Effect in Polyaniline via the Formation of Polyaniline−Clay Nanocomposite Materials
TL;DR: A series of nanocomposite materials that consisted of emeraldine base of polyaniline and layered montmorillonite (MMT) clay were prepared by effectively dispersing the inorganic nanolayers of MMT clay in organic polyanile matrix via in-situ polymerization.
Journal ArticleDOI
An electropolymerized aniline-based fiber coating for solid phase microextraction of phenols from water
TL;DR: In this article, an aniline-based polymer was electrochemically prepared and applied as a new fiber coating for solid phase microextraction (SPME) of some priority phenols from water samples.
Journal ArticleDOI
Thermal properties of chemically synthesized polyaniline (EB) powder
TL;DR: In this article, two glass transitions (T g ), ∼70°C and ∼250°C, were observed for the first time using MDSC during the process of heat treatment.
Journal ArticleDOI
Thermal transporting properties of electrically conductive polyaniline films as organic thermoelectric materials
Hu Yan,Norina Sada,Naoki Toshima +2 more
TL;DR: In this paper, the thermal conductivities of various protonic acid-doped polyaniline films were measured by combination of a laser flash method and a differential scanning calorimeter in relation with electrical conductivity.
Journal ArticleDOI
Chemical Polymerization of Aniline in Hydrochloric Acid (HCl) and Formic Acid (HCOOH) Media. Differences Between the Two Synthesized Polyanilines
E. C. Gomes,M. A. S. Oliveira +1 more
TL;DR: In this paper, conductive polyaniline (doped PAni) was synthesized by a chemical method in media containing, respectively, hydrochloric (HCl) and formic acid (HCOOH).
References
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Book
Mechanical properties of solid polymers
TL;DR: A concise, self-contained introduction to solid polymers, the mechanics of their behavior and molecular and structural interpretations can be found in this article, which provides extended coverage of recent developments in rubber elasticity, relaxation transitions, non-linear viscoelastic behavior, anisotropic mechanical behavior, yield behavior of polymers and other fields.
Journal ArticleDOI
Polyaniline: A historical survey
TL;DR: A survey of the literature available on conducting organic polyaniline can be found in this paper, where the authors provide a survey of some of the most recent work on polyanILine.
Journal ArticleDOI
Resistance of Polyaniline Films as a Function of Electrochemical Potential and the Fabrication of Polyaniline-Based Microelectronic Devices.
TL;DR: In this article, anodic growth of polyaniline films on a Au microelectrode array has been carried out to add to the characterization of polyanoiline and to fabricate polyanoin-based microelectronic devices, diodes and transistors, that function when the polyanoine-functionalized microelectron array is immersed in an electrolyte solution.
Journal ArticleDOI
“Polyaniline”: Interconversion of Metallic and Insulating Forms
Alan G. MacDiarmid,J. C. Chiang,Marc Halpern,W. S. Huang,Shao-Lin Mu,L. D Nanaxakkara,Somasiri Wanqun Wu,Stuart I. Yaniger +7 more
TL;DR: In this paper, the qulnoid-benzenoid-diimine form is doped by dilute aqueous protonic acids to the metallic regime to give the corresponding iminium salt.
Journal ArticleDOI
Infrared spectra of soluble polyaniline
TL;DR: In this article, the infrared spectra of soluble polyaniline (PAn) have been studied and a tentative assignment is given based on the observed effects of HCl concentration in the polymerization system on the i.r.
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‘Polyaniline’: Protonic acid doping of the emeraldine form to the metallic regime
J. C. Chiang,Alan G. MacDiarmid +1 more