scispace - formally typeset
Journal ArticleDOI

THERMOCHROMIC MOLECULES WITH BONDS OF Se OR Te AND Sb OR Bi

Hans Joachim Breunig
- 01 Jul 1988 - 
- Vol. 38, pp 97-102
Reads0
Chats0
TLDR
In this paper, the synthesis and properties of stibino or bismuthino selenides or tellurides of the types R2EE'R, (R2E)2E'R and RE(E"R)2; E = Sb, Bi; E' = Se, Te; R = CH3, C2H5, C6H5 are described.
Abstract: 
The syntheses and properties of stibino or bismuthino selenides or tellurides of the types R2EE'R, (R2E)2E'R, RE(E'R)2; E = Sb, Bi; E' = Se, Te; R = CH3, C2H5, C6H5 are described Reversible change of color with variation of temperature (thermochromism) is observed in the case of (CH3)2SbTeCH3, (C2H5)2SbTeCH3, [(CH3)2Sb]2Se and [(CH3)2Sb]2Te

read more

Citations
More filters
Journal ArticleDOI

Chemical vapour deposition of antimony chalcogenides with positional and orientational control: precursor design and substrate selectivity

Sophie L. Benjamin, +6 more
- 21 Jan 2015 - 
TL;DR: In this article, a series of alkylchalcogenostibines, Me2SbSenBu, MeSb(SenBu)2, Sb(SbSe3), Sb2Te3, SenBu)3 and TenBu2, have been designed and synthesized as potential precursors for chemical vapour deposition (CVD) by reaction of nBuELi (E = Se, Te) with the appropriate halostibine, Me3−nSbCln (n = 1, 2, 3),
Patent

Metal heterocyclic compounds for deposition of thin films

Julien Gatineau, +2 more
TL;DR: In this paper, a metal is deposited on a substrate through a deposition process to form a thin film on the substrate, and a metal containing precursor is provided and introduced into the reactor, which is maintained at a temperature of at least 100° C.
Journal ArticleDOI

Wet-chemical synthesis of different bismuth telluride nanoparticles using metal organic precursors – single source vs. dual source approach

Georg Bendt, +5 more
- 04 Aug 2015 - 
TL;DR: A dual source approach (hot injection method) using the reaction of Te(SiEt3)2 and Bi(NMe2)3 was applied for the synthesis of different pure Bi-Te phases including Bi2Te, Bi4Te3 and Bi2 Te3, which were characterized by PXRD, REM, TEM and EDX.
Patent

Tellurium precursors for film deposition

Shingo Okubo, +2 more
Abstract: Methods and compositions for depositing a tellurium containing film on a substrate are disclosed. A reactor and at least one substrate disposed in the reactor are provided. A tellurium containing precursor is provided and introduced into the reactor, which is maintained at a temperature of at least 100°C. Tellurium is deposited on to the substrate through a deposition process to form a thin film on the substrate.
Journal ArticleDOI

Antimony sources for MOCVD. The use of Et4Sb2 as a p-type dopant for Hg1−xCdxTe and crystal structure of the adduct [Et4Sb2 · 2CdI2]n

Ronald Stanley Dickson, +8 more
- 04 May 1993 - 
TL;DR: Tetraethyldistibine, Et 4 Sb 2, a new antimony source for MOCVD is evaluated as mentioned in this paper, which is shown to be a useful and safe dopant feedstock for low temperature growth of p-type Hg 1- x Cd x Te.
References
More filters
BookDOI

Anwendungen der Schwingungsspektroskopie in der anorganischen Chemie

Hans Siebert
DOI

H. Siebert: Anwendungen der Schwingungsspektroskopie in der anorganischen Chemie. Band VÜ der Reihe „Anorganische und allgemeine Chemie in Einzeldarstellungen”. Springer-Verlag, Berlin-Heidelberg-New York 1966. 209 Seiten, 28 Abbildungen. Preis: DM 39,60

J. Goubeau
Journal ArticleDOI

The exchange reaction of tetramethyldipnictogens with dimethyldichalcogenides

Arthur J. Ashe, +1 more
- 15 Jul 1986 - 
TL;DR: Tetramethyldipnictogens Me4E2 (E = P, As, Sb, Bi) undergo exchange reactions with dimethyldichalcogenides Me2A2 (A = S, Se, Te) to produce the corresponding Me2EAMe.
Journal ArticleDOI

Syntheses of distiba-selenanes, -telluranes and a tellurostibane

Hans Joachim Breunig, +1 more
- 11 Dec 1984 - 
TL;DR: In this paper, the reaction of the distibanes R 4 Sb 2 (R= CH 3, C 2 H 5 ) with selenium or tellurium respectively produces the corresponding distiba-selenanes and -telluranes R 2 SbESbR 2 (E = Se, Te).
Journal ArticleDOI

Reaktionen von Tetrapropyldibismutan mit Chalkogenen und Tetramethyldistiban / Reactions of Tetrapropyldibism uthane with Chalcogens and Tetramethyldistibane

Hans Joachim Breunig, +1 more
- 01 Sep 1986 - 
TL;DR: In this article, Bis(dipropylbismuth)oxide, -sulfide, -selenide and -telluride are obtained by reactions of tetra propyldibismuthane with elem entaloxygen, sulfur, selenium or tellurium.